Spin-exchange collisions of submerged shell atoms below 1 Kelvin

Angular momentum changing collisions can be suppressed in atoms whose valence electrons are submerged beneath filled shells of higher principle quantum number. To determine whether spin-exchange collisions are suppressed in these submerged shell atoms, we measured spin-exchange collisions of six hyperfine states of Mn at temperatures below 1 K. Although the 3d valence electrons in Mn are submerged beneath a filled 4s orbital, we find that the spin exchange rate coefficients are similar to those of Na and H (which are non-submerged shell atoms).