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We present a detailed account of a first-order localization transition in the Discrete Nonlinear Schrodinger Equation, where the localized phase is associated to the high energy region in parameter space. We show that, due to ensemble inequivalence, this phase is thermodynamically stable only in the microcanonical ensemble. In particular, we obtain an explicit expression of the microcanonical entropy close to the transition line, located at infinite temperature. This task is accomplished making use of large-deviation techniques, that allow us to compute, in the limit of large system size, also the subleading corrections to the microcanonical entropy. These subleading terms are crucial ingredients to account for the first-order mechanism of the transition, to compute its order parameter and to predict the existence of negative temperatures in the localized phase. All of these features can be viewed as signatures of a thermodynamic phase where the translational symmetry is broken spontaneously due to a condensation mechanism yielding energy fluctuations far away from equipartition: actually they prefer to participate in the formation of nonlinear localized excitations (breathers), typically containing a macroscopic fraction of the total energy.
The thermodynamics of the discrete nonlinear Schrodinger equation in the vicinity of infinite temperature is explicitly solved in the microcanonical ensemble by means of large-deviation techniques. A first-order phase transition between a thermalized
We discuss how to derive a Langevin equation (LE) in non standard systems, i.e. when the kinetic part of the Hamiltonian is not the usual quadratic function. This generalization allows to consider also cases with negative absolute temperature. We fir
We study stochastic processes in which the trajectories are constrained so that the process realises a large deviation of the unconstrained process. In particular we consider stochastic bridges and the question of inequivalence of path ensembles betw
In a recent paper, Dunkel and Hilbert [Nature Physics 10, 67-72 (2014)] use an entropy definition due to Gibbs to provide a consistent thermostatistics which forbids negative absolute temperatures. Here we argue that the Gibbs entropy fails to satisf
We present a nonrelativistic wave equation for the electron in (3+1)-dimensions which includes negative-energy eigenstates. We solve this equation for three well-known instances, reobtaining the corresponding Pauli equation (but including negative-energy eigenstates) in each case.