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The field electron emission from the single-walled carbon nanotubes with their open ends terminated by -BH, -NH, and -O has been simulated. The apex-vacuum barrier and the emission current have been calculated. It has been found that -BH and -NH suppress the apex-vacuum barrier significantly and lead to higher emission current in contrast to the -O terminated structure in the same applied field. The calculated binding energy implies that the carbon nanotubes terminated with -BH and -NH are more stable than those saturated by oxygen atoms or by hydrogen atoms.
The simulation of field electron emission from arrays of micrometer-long open-ended (5, 5) carbon nanotubes is performed in the framework of quantum theory of many electrons. It is found that the applied external field is strongly screened when the s
Having access to the chemical environment at the atomic level of a dopant in a nanostructure is crucial for the understanding of its properties. We have performed atomically-resolved electron energy-loss spectroscopy to detect individual nitrogen dop
By sequential feeding of catalyst materials, it is revealed that the active growth sites are at the bottom of the carbon nanotubes (CNTs), and that catalyst particles are constantly encapsulated into nanotubes from the bottom. This gives a better ins
Photoluminescence (PL) measurements of porphyrin-doped single wall carbon nanotubes (SWNT) were studied in sodium dodecylbenzenesulfonate (NaDDBS) aqueous dispersions. The PL spectra were used to draw PL maps were the maxima corresponds to absorption
Nitrogen doped carbon nanotubes have been synthesized using pyrolysis and characterized by Scanning Tunneling Spectroscopy and transmission electron microscopy. The doped nanotubes are all metallic and exhibit strong electron donor states near the Fe