ترغب بنشر مسار تعليمي؟ اضغط هنا

Clarification of size effects in polycrystalline BaTiO3 thin films by means of the specific heat measurements: grain size or film thickness?

270   0   0.0 ( 0 )
 نشر من قبل Soulkhan T. Davitadze
 تاريخ النشر 2004
  مجال البحث فيزياء
والبحث باللغة English
 تأليف B. A. Strukov




اسأل ChatGPT حول البحث

Specific heat of polycrystalline BaTiO3 thin films on the fused quartz substrate was measured by ac-hot probe method. Phase transition temperature, excess entropy and spontaneous polarization were determined as a function of film thickness and grain size. The variation of the latter was obtained in the limits 30 - 150 nm by changing of the temperature of the substrate during sputtering while thickness of films 20 - 1100 nm was controlled by the conditions of sputtering. It was found that the relation between the thickness and grain size is important for the size effects in polycrystalline films.



قيم البحث

اقرأ أيضاً

The parameters influencing the band gap of tin sulphide thin nano-crystalline films have been investigated. Both grain size and lattice parameters are known to influence the band gap. The present study initially investigates each contribution individ ually. The experimentally determined dependency on lattice parameter is verified by theoretical calculations. We also suggest how to treat the variation of band gap as a two variable problem. The results allow us to show dependency of effective mass (reduced) on lattice unit volume.
We present the results of a comprehensive study of magnetic, magneto-transport and structural properties of nonstoichiometric MnxSi1-x (x=0.51-0.52) films grown by the Pulsed Laser Deposition (PLD) technique onto Al2O3(0001) single crystal substrates at T = 340{deg}C. A highlight of our PLD method is the using of non-conventional (shadow) geometry with Kr as a scattering gas during the sample growth. It is found that studied films exhibit high-temperature (HT) ferromagnetism (FM) with the Curie temperature TC ~ 370 K accompanied by positive sign anomalous Hall effect (AHE); they also reveal the layered polycrystalline structure with a self-organizing grain size distribution. The HT FM order is originated from the bottom interfacial nanocrystalline layer, while the upper layer possesses the low temperature (LT) type of FM order with TC = 46 K, gives essential contribution to the magnetization below 50 K and is homogeneous on the nanometer size scale. Under these conditions, AHE changes its sign from positive to negative at T < 30 K. We attribute observed properties to the synergy of self-organizing distribution of MnxSi1-x crystallites in size and peculiarities of defect-induced FM order in PLD grown polycrystalline MnxSi1-x (x~0.5) films.
375 - G. Catalan , H. Bea , S. Fusil 2007
We have analyzed the morphology of ferroelectric domains in very thin films of multiferroic BiFeO3. Unlike the more common stripe domains observed in thicker films BiFeO3 or in other ferroics, the domains tend not to be straight, but irregular in sha pe, with significant domain wall roughening leading to a fractal dimensionality. Also contrary to what is usually observed in other ferroics, the domain size appears not to scale as the square root of the film thickness. A model is proposed in which the observed domain size as a function of film thickness can be directly linked to the fractal dimension of the domains.
156 - L. Palova , P. Chandra , K.M. Rabe 2007
We present a segregrated strain model that describes the thickness-dependent dielectric properties of ferroelectric films. Using a phenomenological Landau approach, we present results for two specific materials, making comparison with experiment and with first-principles calculations whenever possible. We also suggest a smoking gun benchtop probe to test our elastic scenario.
We develop a phenomenological thermodynamic theory of ferroelectric BaTiO3 (BT) thin films epitaxially grown on cubic substrates using the Landau-Devonshire eight-order potential. The constructed misfit-temperature phase diagram is asymmetrical. We f ound that, overall view of the phase diagram depends on the values of compliances used in calculations and provide two qualitatively different diagrams. A thermodynamic path for BT film grown onto particular substrate can be found using a plot of the room-temperature tetragonal distortion (c-a)/a as a function of misfit strain.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا