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The smallest polyatomic carbon chain, C$_{3}$, has been identified in interstellar clouds (A$_{v}sim$1 mag) towards $zeta$ Ophiuchi, 20 Aquilae, and $zeta$ Persei by detection of the origin band in its $A^{1}Pi_{u}-X^{1}Sigma^{+}_{g}$ electronic transition, near 4052AA. Individual rotational lines were resolved up to $J$=30 enabling the rotational level column densities and temperature distributions to be determined. The inferred limits for the total column densities ($sim$1 to 2$times10^{12}$ cm$^{-2}$) offer a strong incentive to laboratory and astrophysical searches for the longer carbon chains. Concurrent searches for C$_2^{+}$, C$_2^{-}$ and C$_3^{-}$ were negative but provide sensitive estimates for their maximum column densities.
We investigate the diffuse interstellar band (DIB) spectrum in the interstellar medium of M31. The DEIMOS spectrograph of the W. M. Keck observatory was used to make optical spectroscopic observations of two supergiant stars, MAG 63885 and MAG 70817,
Context. Insight into the conditions that drive the physics and chemistry in interstellar clouds is gained from determining the abundance and charge state of their components. Aims. We propose an evaluation of the C60:C60+ ratio in diffuse and transl
We confirm and discuss recently discovered cold HI clouds with column densities among the lowest ever detected. The column densities of Cold Neutral Medium (CNM) towards 3C286 and 3C287 are ~10^18 cm^-2, below an observational lower limit, and also b
Emission of fullerenes in their infrared vibrational bands has been detected in space near hot stars. The proposed attribution of the diffuse interstellar bands at 9577 and 9632 AA to electronic transitions of the buckminsterfullerene cation (i.e. C$
We report the first detection of C$^{15}$N in diffuse molecular gas from a detailed examination of CN absorption lines in archival VLT/UVES spectra of stars probing local diffuse clouds. Absorption from the C$^{15}$N isotopologue is confidently detec