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A physical model for a mixed-valence impurity in a metal must satisfy the Friedel screening theorem for both valences. Such a model is shown, following earlier work which showed low energy singularities in it, to be supersymmetric, leading to a free Majorana and a phase-shifted Majorana excitation. The theory extended approximately to a lattice of mixed-valence ions at appropriate filling gives, without fine-tuning the parameters, a protected gapless Majorana fermion band across the chemical potential, besides the mixed-valence particle and hole bands separated by gaps. In this situation the system is electrically neutral in linear response but has de Haas-van Alphen oscillations. This is used to explain the recently observed magneto-oscillations in mixed-valence insulators as well as their accompanying low energy thermodynamic and relaxation rate anomalies. Some predictions to test the validity of the theoretical results are provided, the most striking of which is that there should be extensive ground state entropy in such compounds.
Possible topological nature of Kondo and mixed valence insulators has been a recent topic of interest in condensed matter physics. Attention has focused on SmB6, which has long been known to exhibit low temperature transport anomaly, whose origin is
Interacting many-body systems combining confined and extended dimensions, such as ladders and few layer systems are characterized by enhanced quantum fluctuations, which often result in interesting collective properties. Recently two-dimensional bila
The low-temperature electron spin resonance (ESR) spectra and the static magnetization data obtained for the stoichiometric single crystals of $beta$-Na$_{0.33}$V$_2$O$_5$ indicate that this quasi-one-dimensional mixed valence (V4+/V5+) compound demo
Quantum criticality has been considered to be specific to crystalline materials such as heavy fermions. Very recently, however, the Tsai-type quasicrystal Au51Al34Yb15 has been reported to show unusual quantum critical behavior. To obtain a deeper un
Fermi liquid theory, the standard theory of metals, has been challenged by a number of observations of anomalous metallic behavior found in the vicinity of a quantum phase transition. The breakdown of the Fermi liquid is accomplished by fine-tuning t