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Structure-property relationships are the foundation of materials science. Linking microstructure and material properties is essential for predicting material response to driving forces, managing in-service material degradation, and engineering materials for optimal performance. Elastic, thermal, and acoustic properties provide a convenient gateway to directly or indirectly probe material structure across multiple length scales. We review how using the laser-induced transient grating spectroscopy (TGS) technique, which uses a transient diffraction grating to generate surface acoustic waves (SAWs) and temperature gratings on a material surface, non-destructively reveals the material elasticity, thermal diffusivity, and energy dissipation on the sub-microsecond timescale, within a tunable sub-surface depth. This technique has already been applied to many challenging problems in materials characterization, from analysis of radiation damage, to colloidal crystals, to phonon-mediated thermal transport in nanostructured systems, to crystal orientation and lattice parameter determination. Examples of these applications, as well as inferring aspects of microstructural evolution, illustrate the wide potential reach of TGS to solve old materials challenges, and to uncover new science. We conclude by looking ahead at the tremendous potential of TGS for materials discovery and optimization when applied in situ to dynamically evolving systems.
We present new developments of the laser-induced transient grating spectroscopy (TGS) technique that enable the measurement of large area 2D maps of thermal diffusivity and surface acoustic wave speed. Additional capabilities include targeted measure
Nonlinear spectroscopy in the extreme ultraviolet (EUV) and soft x-ray spectral range offers the opportunity for element selective probing of ultrafast dynamics using core-valence transitions (Mukamel et al., Acc. Chem. Res. 42, 553 (2009)). We demon
Optical-domain Transient Grating (TG) spectroscopy is a versatile background-free four-wave-mixing technique used to probe vibrational, magnetic and electronic degrees of freedom in the time domain. The newly developed coherent X-ray Free Electron La
Strong field transient grating spectroscopy has shown to be a very versatile tool in time-resolved molecular spectroscopy. Here we use this technique to investigate the high-order harmonic generation from SF6 molecules vibrationally excited by impuls
The hot disk transient plane source (TPS) method is a widely used standard technique (ISO 22007-2) for the characterization of thermal properties of materials, especially the thermal conductivity, k. Despite its well-established reliability for a wid