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We studied the electrical transport on $beta$-Fe$_{4+delta}$Se$_{5}$ single-crystal nanowires, exhibiting $sqrt{5}timessqrt{5}$ Fe-vacancy order and mixed valence of Fe. We observed a first-order metal-insulator transition of the transition temperature at $sim$28~K at zero magnetic field. The dielectric relaxation reveals that the transition is related to an energy gap expansion of $sim$12~meV, involving the charge-orbital ordering. At nearly 28~K, colossal positive magnetoresistance emerges, resulting from the magnetic-field dependent shift of the transition temperature. Through the transition, the magnetotransport behavior transits from two-dimension-like to one-dimension-like conduction. The transition temperature demonstrates anisotropy with the $c$-axis as the preferred orientation in magnetic fields, suggesting the spin-orbital coupling. Our findings demonstrate the novel magnetoresistive transition intimating a topological transition in the Fe-vacancy-ordered $beta$-Fe$_{4+delta}$Se$_{5}$ nanowires. The results provide valuable information to better understand the orbital nature and the emergence of superconductivity in FeSe-based materials.
The electronic structure of the vacancy-ordered K$_{0.5}$Fe$_{1.75}$Se$_2$ iron-selenide compound (278 phase) is studied using the first-principles density functional method. The ground state of the 278 phase is stripe-like antiferromagnetic, and its
We have carried out a detailed study to investigate the existence of an insulating parent phase for FeSe superconductor. The insulating Fe4Se5 with specific Fe-vacancy order shows a 3D-Mott variable range hopping behavior with a Verwey-like electroni
Vibrational properties of iron-chalcogenide superconductor K$_{0.75}$Fe$_{1.75}$Se$_{2}$ with $T_{c}sim$ 30 K have been measured by Raman and optical spectroscopies over temperature range of 3-300 K. Sample undergoes textit{I4/m} $to $ textit{I4} str
Various Fe-vacancy orders have been reported in tetragonal Fe1-xSe single crystals and nanowires/nanosheets, which are similar to those found in alkali metal intercalated A1-xFe2-ySe2 superconductors. Here we report the in-situ angle-resolved photoem
Several superconducting transition temperatures in the range of 30-40 K were reported in the recently discovered intercalated FeSe sytem (A1-xFe2-ySe2, A = K, Rb, Cs, Tl). Although the superconducting phases were not yet conclusively decided, more th