ﻻ يوجد ملخص باللغة العربية
A detector has been constructed for measuring ion mobilities of gas mixtures at atmospheric pressure and room temperature. The detector consists of a standard triple GEM amplification region and a drift region where ions drift. A method has been developed to measure the ions arrival time at a cathode wire-grid by differentiating the recorded signals on this electrode. Simulations prove that this method is accurate and robust. The ion mobility in different gas mixtures is measured while applying different drift field values ranging from 200 V cm$^{-1}$ to 1100 V cm$^{-1}$. From an extrapolation of a Blancs law fit to measurements in Ar-CO$_2$ mixtures we find the reduced mobility of the drifting (cluster) ion species in pure argon to be $1.94pm0.01$ cm$^{2}$ V$^{-1}$ s$^{-1}$ and in pure carbon-dioxide to be $1.10pm0.01$ cm$^{2}$ V$^{-1}$ s$^{-1}$. Applying the same procedure to our measurements in Ne-CO$_2$ yields $4.06pm0.07$ cm$^{2}$ V$^{-1}$ s$^{-1}$ and $1.09pm0.01$ cm$^{2}$ V$^{- 1}$ s$^{-1}$ for the reduced mobilities in pure neon and carbon-dioxide, respectively. Admixtures of N$_2$ to Ne-CO$_2$ reduce somewhat the mobility. For the baseline gas mixture of the future ALICE Time Projection Chamber, Ne- CO$_2$-N$_{2}$ (90-10-5), the measured reduced mobility of the drifting ions is $2.92pm0.04$ cm$^{2}$ V$^{-1}$ s$^{-1}$. Ion mobilities are examined for different water content ranging from 70 ppm to about 2000 ppm in the gas using Ar-CO$_2$ (90-10) and Ne-CO$_2$ (90-10). A slight decrease of ion mobility is observed for the addition of several hundred ppm of water.
Co$^{2+}$ ions in an octahedral crystal field, stabilise a j$_{eff}$ = 1/2 ground state with an orbital degree of freedom and have been recently put forward for realising Kitaev interactions, a prediction we have tested by investigating spin dynamics
The earliest atmospheres of rocky planets originate from extensive volatile release during magma ocean epochs that occur during assembly of the planet. These establish the initial distribution of the major volatile elements between different chemical
The ionization probability of N$_2$, O$_2$, and CO$_2$ in intense laser fields is studied theoretically as a function of the alignment angle by solving the time-dependent Schrodinger equation numerically assuming only the single-active-electron appro
Diffusion of species in icy dust grain mantles is a fundamental process that shapes the chemistry of interstellar regions; yet measurements of diffusion in interstellar ice analogs are scarce. Here we present measurements of CO diffusion into CO$_2$
CO$_2$ ice is an important reservoir of carbon and oxygen in star and planet forming regions. Together with water and CO, CO$_2$ sets the physical and chemical characteristics of interstellar icy grain mantles, including desorption and diffusion ener