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In this work, we establish a general theory of phase transitions and quantum entanglement in the equilibrium state at arbitrary temperatures. First, we derived a set of universal functional relations between the matrix elements of two-body reduced density matrix of the canonical density matrix and the Helmholtz free energy of the equilibrium state, which implies that the Helmholtz free energy and its derivatives are directly related to entanglement measures because any entanglement measures are defined as a function of the reduced density matrix. Then we show that the first order phase transitions are signaled by the matrix elements of reduced density matrix while the second order phase transitions are witnessed by the first derivatives of the reduced density matrix elements. Near second order phase transition point, we show that the first derivative of the reduced density matrix elements present universal scaling behaviors. Finally we establish a theorem which connects the phase transitions and entanglement at arbitrary temperatures. Our general results are demonstrated in an experimentally relevant many-body spin model.
We study the quantum fidelity approach to characterize thermal phase transitions. Specifically, we focus on the mixed-state fidelity induced by a perturbation in temperature. We consider the behavior of fidelity in two types of second-order thermal p
We study the ground-state entanglement in the quantum Ising model with nearest neighbor ferromagnetic coupling $J$ and find a sequential increase of entanglement depth with growing $J$. This entanglement avalanche starts with two-point entanglement,
We present an example where Spontaneous Symmetry Breaking may effect not only the behavior of the entanglement at Quantum Phase Transitions, but also the origin of the non-analyticity. In particular, in the XXZ model, we study the non analyticities i
Motivated by the quantum adiabatic algorithm (QAA), we consider the scaling of the Hamiltonian gap at quantum first order transitions, generally expected to be exponentially small in the size of the system. However, we show that a quantum antiferroma
A unified description of i) classical phase transitions and their remnants in finite systems and ii) quantum phase transitions is presented. The ensuing discussion relies on the interplay between, on the one hand, the thermodynamic concepts of temper