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Spectroscopic studies of ices in nearby star-forming regions indicate that ice mantles form on dust grains in two distinct steps, starting with polar ice formation (H2O rich) and switching to apolar ice (CO rich). We test how well the picture applies to more diffuse and quiescent clouds where the formation of the first layers of ice mantles can be witnessed. Medium-resolution near-infrared spectra are obtained toward background field stars behind the Pipe Nebula. The water ice absorption is positively detected at 3.0 micron in seven lines of sight out of 21 sources for which observed spectra are successfully reduced. The peak optical depth of the water ice is significantly lower than those in Taurus with the same visual extinction. The source with the highest water-ice optical depth shows CO ice absorption at 4.7 micron as well. The fractional abundance of CO ice with respect to water ice is 16+7-6 %, and about half as much as the values typically seen in low-mass star-forming regions. A small fractional abundance of CO ice is consistent with some of the existing simulations. Observations of CO2 ice in the early diffuse phase of a cloud play a decisive role in understanding the switching mechanism between polar and apolar ice formation.
The Pipe Nebula is a massive, nearby dark molecular cloud with a low star-formation efficiency which makes it a good laboratory to study the very early stages of the star formation process. The Pipe Nebula is largely filamentary, and appears to be th
The Pipe nebula is a massive, nearby, filamentary dark molecular cloud with a low star-formation efficiency threaded by a uniform magnetic field perpendicular to its main axis. It harbors more than a hundred, mostly quiescent, very chemically young s
We present observations of the four hyperfine structure components of the OH 18 cm transition (1612, 1665, 1667 and 1720 MHz) toward a filamentary dark cloud, the Pipe nebula, with the Green Bank Telescope. A statistical equilibrium analysis is appli
The detailed magnetic field structure of the starless dense core CB81 (L1774, Pipe 42) in the Pipe Nebula was determined based on near-infrared polarimetric observations of background stars to measure dichroically polarized light produced by magnetic
We used the new IRAM 30-m FTS backend to perform an unbiased ~15 GHz wide survey at 3 mm toward the Pipe Nebula young diffuse starless cores. We found an unexpectedly rich chemistry. We propose a new observational classification based on the 3 mm mol