ترغب بنشر مسار تعليمي؟ اضغط هنا

Dilatancy of Shear Transformations in a Colloidal Glass

62   0   0.0 ( 0 )
 نشر من قبل M.Q. Jiang
 تاريخ النشر 2017
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

Shear transformations, as fundamental rearrangement events operating in local regions, hold the key of plastic flow of amorphous solids. Despite their importance, the dynamic features of shear transformations are far from clear. Here, we use a colloidal glass under shear as the prototype to directly observe the shear transformation events in real space. By tracing the colloidal particle rearrangements, we quantitatively determine two basic properties of shear transformations: local shear strain and dilatation (or free volume). It is revealed that the local free volume undergoes a significantly temporary increase prior to shear transformations, eventually leading to a jump of local shear strain. We clearly demonstrate that shear transformations have no memory of the initial free volume of local regions. Instead, their emergence strongly depends on the dilatancy ability of these regions, i.e., the dynamic creation of free volume. More specifically, the particles processing the high dilatancy ability directly participate in subsequent shear transformations. These results experimentally support the Argons statement about the dilatancy nature of shear transformations, and also shed insight into the structural origin of amorphous plasticity.



قيم البحث

اقرأ أيضاً

166 - Brian P. Tighe 2013
Shearing stresses can change the volume of a material via a nonlinear effect known as shear dilatancy. We calculate the elastic dilatancy coefficient of soft sphere packings and random spring networks, two canonical models of marginal solids close to their rigidity transition. We predict a dramatic enhancement of dilatancy near rigidity loss in both materials, with a surprising distinction: while packings expand under shear, networks contract. We show that contraction in networks is due to the destabilizing influence of increasing hydrostatic or uniaxial loads, which is counteracted in packings by the formation of new contacts.
Granular packings display the remarkable phenomenon of dilatancy [1], wherein their volume increases upon shear deformation. Conventional wisdom and previous results suggest that dilatancy, as also the related phenomenon of shear-induced jamming, req uires frictional interactions [2, 3]. Here, we investigate the occurrence of dilatancy and shear jamming in frictionless packings. We show that the existence of isotropic jamming densities {phi}j above the minimal density, the J-point density {phi}J [4, 5], leads both to the emergence of shear-induced jamming and dilatancy. Packings at {phi}J form a significant threshold state into which systems evolve in the limit of vanishing pressure under constant pressure shear, irrespective of the initial jamming density {phi}j. While packings for different {phi}j display equivalent scaling properties under compression [6], they exhibit striking differences in rheological behaviour under shear. The yield stress under constant volume shear increases discontinuously with density when {phi}j > {phi}J, contrary to the continuous behavior in generic packings that jam at {phi}J [4, 7].
From soft polymeric gels to hardened cement paste, amorphous solids under constant load exhibit a pronounced time-dependent deformation called creep. The microscopic mechanism of such a phenomenon is poorly understood and constitutes a significant ch allenge in densely packed and chemically reactive granular systems. Both features are prominently present in hydrating cement pastes composed of calcium silicate hydrate (C-S-H) nanoparticles, whose packing density increases as a function of time, while cements hydration is taking place. Performing nano-indentation tests and porosity measurements on a large collection of samples at various hydration degrees, we show that the creep response of hydrating cement paste is mainly controlled by the inter-particle distance, and results from slippage between (C-S-H) nanoparticles. Our findings, which pave the way for the design of concrete with improved creep resistance, provide a unique insight into the microscopic mechanism underpinning the creep response in aging granular materials.
We study the phase ordering dynamics of a two dimensional model colloidal solid using molecular dynamics simulations. The colloid particles interact with each other with a Hamaker potential modified by the presence of equatorial patches of attractive and negative regions. The total interaction potential between two such colloids is, therefore, strongly directional and has three-fold symmetry. Working in the canonical ensemble, we determine the tentative phase diagram in the density-temperature plane which features three distinct crystalline ground states viz, a low density honeycomb solid followed by a rectangular solid at higher density, which eventually transforms to a close packed triangular structure as the density is increased further. We show that when cooled rapidly from the liquid phase along isochores, the system undergoes a transition to a strong glass while slow cooling gives rise to crystalline phases. We claim that geometrical frustration arising from the presence of many crystalline ground states causes glassy ordering and dynamics in this solid. Our results may be easily confirmed by suitable experiments on patchy colloids.
68 - F. Ozon , T. Narita , A. Knaebel 2002
We study the effect of shear on the aging dynamics of a colloidal suspension of synthetic clay particles. We find that a shear of amplitude $gamma$ reduces the relaxation time measured just after the cessation of shear by a factor $exp(-gamma/gamma_c )$, with $gamma_c sim 5%$, and is independent of the duration and the frequency of the shear. This simple law for the rejuvenation effect shows that the energy involved in colloidal rearrangements is proportional to the shear amplitude, $gamma$, rather than $gamma^2$, leading to an Eyring-like description of the dynamics of our system.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا