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We report new correlations between ratios of band intensities of the 15-20 {mu}m emission bands of polycyclic aromatic hydrocarbons (PAHs) in a sample of fifty-seven sources observed with Spitzer/IRS. This sample includes Large Magellanic Cloud point sources from the SAGE-Spec survey, nearby galaxies from the SINGS survey, two Galactic ISM cirrus sources and the spectral maps of the Galactic reflection nebulae NGC 2023 and NGC 7023. We find that the 16.4, 17.4 and 17.8 {mu}m band intensities are inter-correlated in all environments. In NGC 2023 and NGC 7023 these bands also correlate with the 11.0 and 12.7 {mu}m band intensities. The 15.8 {mu}m band correlates only with the 15-20 {mu}m plateau and the 11.2 {mu}m emission. We examine the spatial morphology of these bands and introduce radial cuts. We find that these bands can be spatially organized into three sets: the 12.7, 16.4 and 17.8 {mu}m bands; the 11.2, 15.8 {mu}m bands and the 15-18 {mu}m plateau; and the 11.0 and 17.4 {mu}m bands. We also find that the spatial distribution of the 12.7, 16.4 and 17.8 {mu}m bands can be reconstructed by averaging the spatial distributions of the cationic 11.0 {mu}m and neutral 11.2 {mu}m bands. We conclude that the 17.4 {mu}m band is dominated by cations, the 15.8 {mu}m band by neutral species, and the 12.7, 16.4 and 17.8 {mu}m bands by a combination of the two. These results highlight the importance of PAH ionization for spatially differentiating sub-populations by their 15-20 {mu}m emission variability.
Context. The 3.3 $mu$m aromatic C-H stretching band of polycyclic aromatic hydrocarbon (PAH) molecules seen in a wide variety of astrophysical regions is often accompanied by a series of weak satellite bands at ~3.4-3.6 $mu$m. One of these sources, I
We present a new method to accurately describe the ionization fraction and the size distribution of polycyclic aromatic hydrocarbons (PAHs) within astrophysical sources. To this purpose, we have computed the mid-infrared emission spectra of 308 PAH m
We report new properties of the 11 and 12.7 {mu}m emission complexes of polycyclic aromatic hydrocarbons (PAHs) by applying a Gaussian-based decomposition technique. Using high-resolution textit{Spitzer} Space Telescope data, we study in detail the s
The amount of deuterium locked up in polycyclic aromatic hydrocarbons (PAHs) has to date been an uncertain value. We present a near-infrared (NIR) spectroscopic survey of HII regions in the Milky Way, Large Magellanic Cloud (LMC), and Small Magellani
The cosmic-ray ionization rate ($zeta$, s$^{-1}$) plays an important role in the interstellar medium. It controls ion-molecular chemistry and provides a source of heating. Here we perform a grid of calculations using the spectral synthesis code CLOUD