ترغب بنشر مسار تعليمي؟ اضغط هنا

The model of stress distribution in polymer electrolyte membrane

156   0   0.0 ( 0 )
 نشر من قبل Vadim Atrazhev V.
 تاريخ النشر 2014
  مجال البحث فيزياء
والبحث باللغة English




اسأل ChatGPT حول البحث

An analytical model of mechanical stress in a polymer electrolyte membrane (PEM) of a hydrogen/air fuel cell with porous Water Transfer Plates (WTP) is developed in this work. The model considers a mechanical stress in the membrane is a result of the cell load cycling under constant oxygen utilization. The load cycling causes the cycling of the inlet gas flow rate, which results in the membrane hydration/dehydration close to the gas inlet. Hydration/dehydration of the membrane leads to membrane swelling/shrinking, which causes mechanical stress in the constrained membrane. Mechanical stress results in through-plane crack formation. Thereby, the mechanical stress in the membrane causes mechanical failure of the membrane, limiting fuel cell lifetime. The model predicts the stress in the membrane as a function of the cell geometry, membrane material properties and operation conditions. The model was applied for stress calculation in GORE-SELECT.



قيم البحث

اقرأ أيضاً

A carbon corrosion model is developed based on the formation of surface oxides on carbon and platinum of the polymer electrolyte membrane fuel cell electrode. The model predicts the rate of carbon corrosion under potential hold and potential cycling conditions. The model includes the interaction of carbon surface oxides with transient species like OH radicals to explain observed carbon corrosion trends under normal PEM fuel cell operating conditions. The model prediction agrees qualitatively with the experimental data supporting the hypothesis that the interplay of surface oxide formation on carbon and platinum is the primary driver of carbon corrosion.
Direct simulation of biomolecular dynamics in thermal equilibrium is challenging due to the metastable nature of conformation dynamics and the computational cost of molecular dynamics. Biased or enhanced sampling methods may improve the convergence o f expectation values of equilibrium probabilities and expectation values of stationary quantities significantly. Unfortunately the convergence of dynamic observables such as correlation functions or timescales of conformational transitions relies on direct equilibrium simulations. Markov state models are well suited to describe both, stationary properties and properties of slow dynamical processes of a molecular system, in terms of a transition matrix for a jump process on a suitable discretiza- tion of continuous conformation space. Here, we introduce statistical estimation methods that allow a priori knowledge of equilibrium probabilities to be incorporated into the estimation of dynamical observables. Both, maximum likelihood methods and an improved Monte Carlo sampling method for reversible transition ma- trices with fixed stationary distribution are given. The sampling approach is applied to a toy example as well as to simulations of the MR121-GSGS-W peptide, and is demonstrated to converge much more rapidly than a previous approach in [F. Noe, J. Chem. Phys. 128, 244103 (2008)]
We report on a periodic precipitation pattern emerged from a drying meniscus via evaporation of a polystyrene solution in a Petri dish. It appeared a quasi-logarithmic spacing relation in the pattern as a result of stick-slip motion of the contact li ne towards the wall. A model based on the dynamics of the evaporating meniscus is proposed.
Structure of polymer electrolytes membranes, e.g., Nafion, inside fuel cell catalyst layers has significant impact on the electrochemical activity and transport phenomena that determine cell performance. In those regions, Nafion can be found as an ul tra-thin film, coating the catalyst and the catalyst support surfaces. The impact of the hydrophilic/hydrophobic character of these surfaces on the structural formation of the films and, in turn, on transport properties, has not been sufficiently explored yet. Here, we report about classical Molecular Dynamics simulations of hydrated Nafion thin-films in contact with unstructured supports, characterized by their global wetting properties only. We have investigated structure and transport in different regions of the film and found evidences of strongly heterogeneous behavior. We speculate about the implications of our work on experimental and technological activity.
53 - C.H.Wong , L.Xue , E.A.Buntov 2018
The Monte Carlo carbyne model is modified to investigate the glass transition of the semi-flexible entangled polymer chains. The stochastic bombardment between monomers are monitored by Metropolis algorithm with help of the consideration of hard pote ntial while the mobility of monomers is governed by its mass, scattering rate and temperature. Our model is capable to show that the glass transition temperature reduces with decreasing film thickness and the formation of critical voids in the thinner polymer contributing to the glass transition that is much easier than the bulk polymer.
التعليقات
جاري جلب التعليقات جاري جلب التعليقات
سجل دخول لتتمكن من متابعة معايير البحث التي قمت باختيارها
mircosoft-partner

هل ترغب بارسال اشعارات عن اخر التحديثات في شمرا-اكاديميا