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تسجيل مستخدم جديدFracture Strength of AlLiB14
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The orthorhombic boride crystal family XYB$_{14}$, where X and Y are metal atoms, plays a critical role in a unique class of superhard compounds, yet there have been no studies aimed at understanding the origin of the mechanical strength of this compound. We present here the results from a comprehensive investigation into the fracture strength of the archetypal AlLiB$_{14}$ crystal. First-principles, textit{ab initio}, methods are used to determine the ideal brittle cleavage strength for several high-symmetry orientations. The elastic tensor and the orientation-dependent Youngs modulus are calculated. From these results the lower bound fracture strength of AlLiB$_{14}$ is predicted to be between 29 and 31 GPa, which is near the measured hardness reported in the literature. These results indicate that the intrinsic strength of AlLiB$_{14}$ is limited by the interatomic B--B bonds that span between the B layers.
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