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The thermal vacuum treatment effect on the optical absorption spectra of the TiO2 nanopowders, both pure and coated by the Ni-B clasters with the original electroless method was investigated. It was observed that the thermal treatment of pure TiO2 nanopowders does not change their optical absorption spectrum while after the coating of these powder particles by the Ni-B clasters the thermal treatment results in the increase of the optical light absorption in the visual region of spectrum. This points to the possibility of the significant improvement of the photocatalist efficiency of TiO2 nanopowders coated by the Ni-B clasters using the thermal treatment.
To investigate excess-hydrolysis of titanium alkoxides, TiO2 powders were fabricated from titanium-tetra-isopropoxide using 6:1 and 100:1 H2O:Ti (r) ratios. Powders were dried and fired at a range of temperatures ( up to 800 C). Hydroxylation and org
Results obtained from the optical absorption and photoluminescence (PL) spectroscopy experiments have shown the formation of excitons in the silver-exchanged glass samples. These findings are reported here for the first time. Further, we investigate
The linear polarizability absorption spectra of the double-walled carbon nanotubes (DWNTs) have been calculated by using the tight-binding (TB) model and sum-over-state (SOS) method, supplemented by the first principles CASTEP calculations. It is fou
Phase transition from anatase to rutile for the 70nm TiO2 crystallite has been investigated by annealing at different temperatures followed by TDPAC measurement of these TiO2 crystallites adsorbed with 181Hf tracer. The width of the peaks in XRD spec
The Raman effect -- inelastic scattering of light by lattice vibrations (phonons) -- produces an optical response closely tied to a materials crystal structure. Here we show that resonant optical excitation of IR and Raman phonons gives rise to a Ram