We have studied thermal chaotic behavior in the extended phase space for a charged dilaton-AdS black hole by Melnikov method and present the effect of dilaton parameter on the thermal chaos. Our result show that for the temporal perturbation the thermal chaos in the charged dilaton-AdS black hole occurs only if the perturbation amplitude is larger than certain a critical value, but for the spatially perturbation, the chaos always exists irrespective of perturbation amplitude. These behaviors are similar to those in other AdS black hole, which can be regarded as the common features of the static AdS black holes. Moreover, we also find that the critical temporal perturbation amplitude leading to chaos increases with the dilaton parameter and decreases with the charge. This means that under the temporal perturbation the presence of dilaton parameter makes the onset of chaos more difficult, which differs from that of the charge parameter.
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