We present the first release of the MaNGA Stellar Library (MaStar), which is a large, well-calibrated, high-quality empirical library covering the wavelength range of 3,622-10,354A at a resolving power of R~1800. The spectra were obtained using the same instrument as used by the Mapping Nearby Galaxies at Apache Point Observatory (MaNGA) project, by piggybacking on the SDSS-IV/APOGEE-2N observations. Compared to previous empirical libraries, the MaStar library will have a higher number of stars and a more comprehensive stellar-parameter coverage, especially of cool dwarfs, low-metallicity stars, and stars with different [alpha/Fe], achieved by a sophisticated target selection strategy that takes advantage of stellar-parameter catalogs from the literature. This empirical library will provide a new basis for stellar population synthesis, and is particularly well-suited for stellar-population analysis of MaNGA galaxies. The first version of the library contains 8646 high-quality per-visit spectra for 3321 unique stars. Compared to photometry, the relative flux calibration of the library is accurate to 3.9% in g-r, 2.7% in r-i, and 2.2% in i-z. The data are released as part of Sloan Digital Sky Survey Data Release 15. We expect the final release of the library to contain more than 10,000 stars.
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