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Bound States of Defects in Superconducting LiFeAs Studied by Scanning Tunneling Spectroscopy

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 Added by Sarah Burke
 Publication date 2012
  fields Physics
and research's language is English




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Defects in LiFeAs are studied by scanning tunneling microscopy (STM) and spectroscopy (STS). Topographic images of the five predominant defects allow the identification of their position within the lattice. The most commonly observed defect is associated with an Fe site and does not break the local lattice symmetry, exhibiting a bound state near the edge of the smaller gap in this multi-gap superconductor. Three other common defects, including one also on an Fe site, are observed to break local lattice symmetry and are pair-breaking indicated by clear in-gap bound states, in addition to states near the smaller gap edge. STS maps reveal complex, extended real-space bound state patterns, including one with a chiral distribution of the local density of states (LDOS). The multiple bound state resonances observed within the gaps and at the inner gap edge are consistent with theoretical predictions for s$^{pm}$ gap symmetry proposed for LiFeAs and other iron pnictides.



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We present a microscopic investigation of frequently observed impurity-induced states in stoichiometric LiFeAs using low temperature scanning tunneling microscopy and spectroscopy (STM/STS). Our data reveal seven distinct well defined defects which are discernible in topographic measurements. Depending on their local topographic symmetry, we are able to assign five defect types to specific lattice sites at the Li, Fe and As positions. The most prominent result is that two different defect types have a remarkably different impact on the superconducting state. A specific and quite abundant Fe-defect with $D_2$-symmetry generates significant impurity-induced additional states primarily at positive bias voltage with pronounced peaks in the on-site local density of states (LDOS) at about 4~mV and 12~mV. On the other hand, a $D_4$-symmetric As-defect causes a significantly enhanced LDOS at both positive and negative bias voltages. We expect that these findings provide fresh input for further experimental and theoretical studies on elucidating the nature of superconductivity in LiFeAs.
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