We will study the angle sums of polytopes, listed in the $alpha$-vector, working to exploit the analogy between the f-vector of faces in each dimension and the alpha-vector of angle sums. The Gram and Perles relations on the $alpha$-vector are analogous to the Euler and Dehn-Sommerville relations on the f-vector. First we describe the spaces spanned by the the alpha-vector and the $alpha$-f-vectors of certain classes of polytopes. Families of polytopes are constructed whose angle sums span the spaces of polytopes defined by the Gram and Perles equations. This shows that the dimension of the affine span of the space of angle sums of simplices is floor[(d-1)/2], and that of the combined angle sums and face numbers of simplicial polytopes and general polytopes are d-1 and 2d-3, respectively. Next we consider angle sums of polytopal complexes. We define the angle characteristic on the alpha-vector in analogy to the Euler characteristic. We show that the changes in the two correspond and that, in the case of certain odd-dimensional polytopal complexes, the angle characteristic is half the Euler characteristic. Finally, we consider spherical and hyperbolic polytopes and polytopal complexes. Spherical and hyperbolic analogs of the Gram relation and a spherical analog of the Perles relation are known, and we show the hyperbolic analog of the Perles relations in a number of cases. Proving this relation for simplices of dimension greater than 3 would finish the proof of this result. Also, we show how constructions on spherical and hyperbolic polytopes lead to corresponding changes in the angle characteristic and Euler characteristic.
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