The asymptotic expansion of the heat-kernel for small values of its argument has been studied in many different cases and has been applied to 1-loop calculations in Quantum Field Theory. In this thesis we consider this asymptotic behavior for certain singular differential operators which can be related to quantum fields on manifolds with conical singularities. Our main result is that, due to the existence of this singularity and of infinitely many boundary conditions of physical relevance related to the admissible behavior of the fields on the singular point, the heat-kernel has an unusual asymptotic expansion. We describe examples where the heat-kernel admits an asymptotic expansion in powers of its argument whose exponents depend on external parameters. As far as we know, this kind of asymptotics had not been found and therefore its physical consequences are still unexplored.
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