We present the X-ray data and the optical identifications for a deep ROSAT PSPC observation in the Marano field. In the inner region of the ROSAT field (15 radius) we detected 50 X-ray sources with Sx >= 3.7x10^(-15) erg/cm^2/s. When corrected for the different sensitivity over the field, the estimated observed surface density at Sx >= 4x10^(-15) erg/cm^2/s is 272+/-40 sources/sq.deg. Four X-ray sources, corresponding to 8% of the total sample, have been detected in radio images with a flux limit of about 0.2 mJy. Careful statistical analysis of multicolour CCD data in the error boxes of the 50 X-ray sources has led to the identification of 42 sources, corresponding to 84% of the X-ray sample. These 42 reliable identifications are 33 AGNs (including two radio galaxies and one BL Lac candidate; 79% of the identified sources), 2 galaxies, 3 groups or clusters of galaxies and 4 stars. We also show that it is likely that a few of the 8 unidentified sources are such because the derived X-ray positions may be offset with respect to the real ones due to confusion effects. The unidentified sources have a large ratio of X-ray to optical fluxes and most of them have harder than average X-ray spectra. Since most of the identified objects with these characteristics in our field and in the Lockman field are AGNs, we conclude that also most of these sources are likely to be AGNs. Finally, comparing the optically and X-ray selected samples of AGNs in this field, we estimate the ``efficiency of AGN selection with deep X-ray exposures and with purely optical criteria.