Cooperative Adaptive Cruise Control (CACC) is an autonomous vehicle-following technology that allows groups of vehicles on the highway to form in tightly-coupled platoons. This is accomplished by exchanging inter-vehicle data through Vehicle-to-Vehicle (V2V) wireless communication networks. CACC increases traffic throughput and safety, and decreases fuel consumption. However, the surge of vehicle connectivity has brought new security challenges as vehicular networks increasingly serve as new access points for adversaries trying to deteriorate the platooning performance or even cause collisions. In this manuscript, we propose a novel attack detection scheme that leverage real-time sensor/network data and physics-based mathematical models of vehicles in the platoon. Nevertheless, even the best detection scheme could lead to conservative detection results because of unavoidable modelling uncertainties, network effects (delays, quantization, communication dropouts), and noise. It is hard (often impossible) for any detector to distinguish between these different perturbation sources and actual attack signals. This enables adversaries to launch a range of attack strategies that can surpass the detection scheme by hiding within the system uncertainty. Here, we provide risk assessment tools (in terms of semidefinite programs) for Connected and Automated Vehicles (CAVs) to quantify the potential effect of attacks that remain hidden from the detector (referred here as emph{stealthy attacks}). A numerical case-study is presented to illustrate the effectiveness of our methods.