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Register a new userQuantum Parametric Oscillator Heat Engines in Squeezed Thermal Baths: Foundational Theoretical Issues
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In this paper we examine some foundational issues of a class of quantum engines where the system consists of a single quantum parametric oscillator, operating in an Otto cycle consisting of 4 stages of two alternating phases: the isentropic phase is detached from any bath (thus a closed system) where the natural frequency of the oscillator is changed from one value to another, and the isothermal phase where the system (now rendered open) is put in contact with one or two squeezed baths of different temperatures, whose nonequilibrium dynamics follows the Hu-Paz-Zhang (HPZ) master equation for quantum Brownian motion. The HPZ equation is an exact nonMarkovian equation which preserves the positivity of the density operator and is valid for a) all temperatures, b) arbitrary spectral density of the bath, and c) arbitrary coupling strength between the system and the bath. Taking advantage of these properties we examine some key foundational issues of theories of quantum open and squeezed systems for these two phases of the quantum Otto engines. This include, i) the nonMarkovian regimes for non-Ohmic, low temperature baths, ii) what to expect in nonadiabatic frequency modulations, iii) strong system-bath coupling, as well as iv) the proper junction conditions between these two phases. Our aim here is not to present ways for attaining higher efficiency but to build a more solid theoretical foundation for quantum engines of continuous variables covering a broader range of parameter spaces hopefully of use for exploring such possibilities.
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In this paper we study the nonequilibrium evolution of a quantum Brownian oscillator, modeling the internal degree of freedom of a harmonic atom or an Unruh-DeWitt detector, coupled to a nonequilibrium, nonstationary quantum field and inquire whether a fluctuation-dissipation relation can exist after/if it approaches equilibration. This is a nontrivial issue since a squeezed bath field cannot reach equilibration and yet, as this work shows, the system oscillator indeed can, which is a necessary condition for FDRs. We discuss three different settings: A) The bath field essentially remains in a squeezed thermal state throughout, whose squeeze parameter is a mode- and time-independent constant. This situation is often encountered in quantum optics and quantum thermodynamics. B) The field is initially in a thermal state, but subjected to a parametric process leading to mode- and time-dependent squeezing. This scenario is met in cosmology and dynamical Casimir effect. The squeezing in the bath in both types of processes will affect the oscillators nonequilibrium evolution. We show that at late times it approaches equilibration, which warrants the existence of an FDR. The trait of squeezing is marked by the oscillators effective equilibrium temperature, and the factor in the FDR is only related to the stationary component of baths noise kernel. Setting C) is more subtle: A finite system-bath coupling strength can set the oscillator in a squeezed state even the bath field is stationary and does not engage in any parametric process. The squeezing of the system in this case is in general time-dependent but becomes constant when the internal dynamics is fully relaxed. We begin with comments on the broad range of physical processes involving squeezed thermal baths and end with some remarks on the significance of FDRs in capturing the essence of quantum backreaction in nonequilibrium systems.
The efficiency of small thermal machines is typically a fluctuating quantity. We here study the efficiency large deviation function of two exemplary quantum heat engines, the harmonic oscillator and the two-level Otto cycles. While the efficiency statistics follows the universal theory of Verley et al. [Nature Commun. 5, 4721 (2014)] for nonadiabatic driving, we find that the latter framework does not apply in the adiabatic regime. We relate this unusual property to the perfect anticorrelation between work output and heat input that generically occurs in the broad class of scale-invariant adiabatic quantum Otto heat engines and suppresses thermal as well as quantum fluctuations.
We consider a thermal quantum harmonic oscillator weakly coupled to a heat bath at a different temperature. We analytically study the quantum heat exchange statistics between the two systems using the quantum-optical master equation. We exactly compute the characteristic function of the heat distribution and show that it verifies the Jarzynski-Wojcik fluctuation theorem. We further evaluate the heat probability density in the limit of long thermalization times, both in the low and high temperature regimes, and investigate its time evolution by calculating its first two cumulants.
The heat engine, a machine that extracts useful work from thermal sources, is one of the basic theoretical constructs and fundamental applications of classical thermodynamics. The classical description of a heat engine does not include coherence in its microscopic degrees of freedom. By contrast, a quantum heat engine might possess coherence between its internal states. Although the Carnot efficiency cannot be surpassed, and coherence can be performance degrading in certain conditions, it was recently predicted that even when using only thermal resources, internal coherence can enable a quantum heat engine to produce more power than any classical heat engine using the same resources. Such a power boost therefore constitutes a quantum thermodynamic signature. It has also been shown that the presence of coherence results in the thermodynamic equivalence of different quantum heat engine types, an effect with no classical counterpart. Microscopic heat machines have been recently implemented with trapped ions, and proposals for heat machines using superconducting circuits and optomechanics have been made. When operated with standard thermal baths, however, the machines implemented so far have not demonstrated any inherently quantum feature in their thermodynamic quantities. Here we implement two types of quantum heat engines by use of an ensemble of nitrogen-vacancy centres in diamond, and experimentally demonstrate both the coherence power boost and the equivalence of different heat-engine types. This constitutes the first observation of quantum thermodynamic signatures in heat machines.
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