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Register a new userKnowledge Gaps in the Cometary Spectra of Oxygen-Bearing Molecular Cations
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Molecular cations are present in various astronomical environments, most notably in cometary atmospheres and tails where sunlight produces exceptionally bright near-UV to visible transitions. Such cations typically have longer-wavelength and brighter electronic emission than their corresponding neutrals. A robust understanding of their near-UV to visible properties would allow these cations to be used as tools for probing the local plasma environments or as tracers of neutral gas in cometary environments. However, full spectral models are not possible for characterization of small, oxygen containing molecular cations given the body of molecular data currently available. The five simplest such species (H2O+, CO+2 , CO+, OH+, and O+2 ) are well characterized in some spectral regions but are lacking robust reference data in others. Such knowledge gaps hinder fully quantitative models of cometary spectra, specifically, hindering accurate estimates of physical-chemical processes originating with the most common molecules in comets. Herein the existing spectral data are collected for these molecules and highlight the places where future work is needed, specifically where the lack of such data would greatly enhance the understanding of cometary evolution.
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We study the visible and near-infrared (NIR) spectral properties of different ACO populations and compare them to the independently determined properties of comets. We select our ACOs sample based on published dynamical criteria and present our own observational results obtained using the 10.4m Gran Telescopio Canarias (GTC), the 4.2m William Herschel Telescope (WHT), the 3.56m Telescopio Nazionale Galileo (TNG), and the 2.5m Isaac Newton Telescope (INT), all located at the El Roque de los Muchachos Observatory (La Palma, Spain), and the 3.0m NASA Infrared Telescope Facility (IRTF), located at the Mauna Kea Observatory, in Hawaii. We include in the analysis the spectra of ACOs obtained from the literature. We derive the spectral class and the visible and NIR spectral slopes. We also study the presence of hydrated minerals by studying the 0.7 $mu$m band and the UV-drop below 0.5 $mu$m associated with phyllosilicates. We present new observations of 17 ACOs, 11 of them observed in the visible, 2 in the NIR and 4 in the visible and NIR. We also discuss the spectra of 12 ACOs obtained from the literature. All but two ACOs have a primitive-like class spectrum (X or D-type). Almost 100% of the ACOs in long-period cometary orbits (Damocloids) are D-types. Those in Jupiter family comet orbits (JFC-ACOs) are $sim$ 60% D-types and $sim$ 40% X-types. The mean spectral slope $S$ of JFC-ACOs is 9.7 $pm$ 4.6 %/1000 AA and for the Damocloids this is 12.2 $pm$ 2.0 %/1000 AA . No evidence of hydration on the surface of ACOs is found from their visible spectra. The slope and spectral class distribution of ACOs is similar to that of comets. The spectral classification, the spectral slope distribution of ACOs, and the lack of spectral features indicative of the presence of hydrated minerals on their surface, strongly suggest that ACOs are likely dormant or extinct comets.
Filamentary enstatite crystals are found in interplanetary dust particles of likely cometary origin but are very rare or absent in meteorites. Crystallographic characteristics of filamentary enstatites indicate that they condensed directly from vapor. We measured the O isotopic composition of an enstatite ribbon from a giant cluster interplanetary dust particle to be $delta^{18}rm{O}{=25{pm}55}$, $delta^{17}rm{O}{=-19{pm}129}$, $Delta^{17}rm{O}{=-32{pm}134}$ (2$sigma$ errors), which is inconsistent at the 2$sigma$ level with the composition of the Sun inferred from the Genesis solar wind measurements. The particles O isotopic composition, consistent with the terrestrial composition, implies that it condensed from a gas of non-solar O isotopic composition, possibly as a result of vaporization of disk region enriched in $^{16}$O-depleted solids. The relative scarcity of filamentary enstatite in asteroids compared to comets implies either that this crystal condensed from dust vaporized textit{in-situ} in the outer Solar System where comets formed, or it condensed in the inner Solar System and was subsequently transported outward to the comet-forming region.
We present the detection of new cometary X-ray emission lines in the 1.0 to 2.0 keV range using a sample of comets observed with the Chandra X-ray observatory and ACIS spectrometer. We have selected 5 comets from the Chandra sample with good signal-to-noise spectra. The surveyed comets are: C/1999 S4 (LINEAR), C/1999 T1 (McNaught-Hartley), 153P/2002 (Ikeya-Zhang), 2P/2003 (Encke), and C/2008 8P (Tuttle). We modeled the spectra with an extended version of our solar wind charge exchange (SWCX) emission model (Bodewits et al. 2007). Above 1 keV, we find Ikeya-Zhang to have strong emission lines at 1340 and 1850 eV that we identify as being created by solar wind charge exchange lines of Mg XI and Si XIII, respectively, and weaker emission lines at 1470, 1600, and 1950 eV formed by SWCX of Mg XII, Mg XI, and Si XIV, respectively. The Mg XI and XII and Si XIII and XIV lines are detected at a significant level for the other comets in our sample (LS4, MH, Encke, 8P), and these lines promise additional diagnostics to be included in SWCX models. The silicon lines in the 1700 to 2000 eV range are detected for all comets, but with the rising background and decreasing cometary emission, we caution these detections need further confirmation with higher resolution instruments.
Molecular oxygen has been detected in the coma of comet 67P/Churyumov-Gerasimenko with abundances in the 1-10% range by the ROSINA-DFMS instrument on board the Rosetta spacecraft. Here we find that the radiolysis of icy grains in low-density environments such as the presolar cloud may induce the production of large amounts of molecular oxygen. We also show that molecular oxygen can be efficiently trapped in clathrates formed in the protosolar nebula, and that its incorporation as crystalline ice is highly implausible because this would imply much larger abundances of Ar and N2 than those observed in the coma. Assuming that radiolysis has been the only O2 production mechanism at work, we conclude that the formation of comet 67P/Churyumov-Gerasimenko is possible in a dense and early protosolar nebula in the framework of two extreme scenarios: (1) agglomeration from pristine amorphous icy grains/particles formed in ISM and (2) agglomeration from clathrates that formed during the disks cooling. The former scenario is found consistent with the strong correlation between O2 and H2O observed in 67P/C-Gs coma while the latter scenario requires that clathrates formed from ISM icy grains that crystallized when entering the protosolar nebula.
Recently the ROSINA mass spectrometer suite on board the European Space Agencys Rosetta spacecraft discovered an abundant amount of molecular oxygen, O2, in the coma of Jupiter family comet 67P/Churyumov-Gerasimenko of O2/H2O = 3.80+/-0.85%. It could be shown that O2 is indeed a parent species and that the derived abundances point to a primordial origin. One crucial question is whether the O2 abundance is peculiar to comet 67P/Churyumov-Gerasimenko or Jupiter family comets in general or whether also Oort cloud comets such as comet 1P/Halley contain similar amounts of molecular oxygen. We investigated mass spectra obtained by the Neutral Mass Spectrometer instrument obtained during the flyby by the European Space Agencys Giotto probe at comet 1P/Halley. Our investigation indicates that a production rate of O2 of 3.7+/-1.7% with respect to water is indeed compatible with the obtained Halley data and therefore that O2 might be a rather common and abundant parent species.
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