Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userNeutral dissociation of methane by electron impact and a complete and consistent cross section set
51
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We present cross sections for the neutral dissociation of methane, in a large part obtained through analytical approximations. With these cross sections the work of Song $textit{et al.}$ [J. Phys. Chem. Ref. Data, $textbf{44}$, 023101, (2015)] can be extended which results in a complete and consistent set of cross sections for the collision of electrons with up to 100 eV energy with methane molecules. Notably, the resulting cross section set does not require any data fitting to produce bulk swarm parameters that match with experiments. Therefore consistency can be considered an inherent trait of the set, since swarm parameters are used exclusively for validation of the cross sections. Neutral dissociation of methane is essential to include (1) because it is a crucial electron energy sink in methane plasma, and (2) because it largely contributes to the production of hydrogen radicals that can be vital for plasma-chemical processes. Finally, we compare the production rates of hydrogen species for a swarm-fitted data set with ours. The two consistent cross section sets predict different production rates, with differences of $45%$ (at $100$ Td) and $125%$ (at $50$ Td) for production of H$_2$ and a similar trend for production of H. With this comparison we underline that the swarm-fitting procedure, used to ensure consistency of the electron swarm parameters, can possibly deteriorate the accuracy with which chemical production rates are estimated. This is of particular importance for applications with an emphasis on plasma-chemical activation of the gas.
rate research
Read More
The electron impact ionization of atomic hydrogen is calculated for incident elrctron energy 76.46 eV. The Hartree-Fock approximation is used to calculate the initial state which includes both bound and continum wave functions. The final state continuum electron wave functions are obtained in the potential of hydrogen ion. The interaction between the two final state continuum electrons is approximated with the screening potential determined variationally.
Net ionization and net capture cross-section calculations are presented for proton collisions from methane molecules and the DNA/RNA nucleobases adenine, cytosine, guanine, thymine, and uracil. We use the recently introduced independent-atom-model pixel counting method to calculate these cross sections in the 10 keV to 10 MeV impact energy range and compare them with results obtained from the simpler additivity rule, a previously used complete-neglect-of-differential-overlap method, and with experimental data and previous calculations where available. It is found that all theoretical results agree reasonably well at high energies, but deviate significantly in the low-to-intermediate energy range. In particular, the pixel counting method which takes the geometrical overlap of atomic cross sections into account is the only calculation that is able to describe the measurements for capture in proton-methane collisions down to 10 keV impact energy. For the nucleobases it also yields a significantly smaller cross section in this region than the other models. New measurements are urgently required to test this prediction.
We have measured electron impact ionization (EII) for Fe 7+ from the ionization threshold up to 1200 eV. The measurements were performed using the TSR heavy ion storage ring. The ions were stored long enough prior to measurement to remove most metastables, resulting in a beam of 94% ground state ions. Comparing with the previously recommended atomic data, we find that the Arnaud & Raymond (1992) cross section is up to about 40% larger than our measurement, with the largest discrepancies below about 400~eV. The cross section of Dere (2007) agrees to within 10%, which is about the magnitude of the experimental uncertainties. The remaining discrepancies between measurement and the most recent theory are likely due to shortcomings in the theoretical treatment of the excitation-autoionization contribution.
We compute inclusive electron-nucleus cross sections using ab initio spectral functions of $^4$He and $^{16}$O obtained within the Self Consistent Greens Function approach. The formalism adopted is based on the factorization of the spectral function and the nuclear transition matrix elements. This allows to provide an accurate description of nuclear dynamics and to account for relativistic effects in the interaction vertex. Our calculations use a saturating chiral Hamiltonian in order reproduce the correct nuclear sizes. When final state interactions for the struck particle are accounted for, we find nice agreement between the data and the theory for the inclusive electron-$^{16}$O cross section. The results lay the foundations for future applications of the Self Consistent Greens Function method, in both closed and open shell nuclei, to neutrino data analysis. This work also presents results for the point-proton, charge and single-nucleon momentum distribution of the same two nuclei. The center of mass can affect these quantities for light nuclei and cannot be separated cleanly in most ab initio post-Hartree-Fock methods. In order to address this, we developed a Metropolis Monte Carlo calculation in which the center of mass coordinate can be subtracted exactly from the trial wave function and the expectation values. We gauged this effect for $^4$He by removing the center of mass effect from the Optimal Reference State wave function that is generated during the Self Consistent Greens Function calculations. Our findings clearly indicate that the residual center of mass contribution strongly modifies calculated matter distributions with respect to those obtained in the intrinsic frame. Hence, its subtraction is crucial for a correct description of light nuclei.
A theoretical investigation of the dissociative excitation by electron impact on the NO molecule is presented, aiming to make up for the lack of data for this process in the literature. A full set of vibrationally-resolved cross sections and corresponding rate coefficients are calculated using the Local-Complex-Potential approach and five resonant states of NO^-.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
