Primordial black holes (PBHs) from the early Universe have been connected with the nature of dark matter and can significantly affect cosmological history. We show that coincidence dark radiation and density fluctuation gravitational wave signatures associated with evaporation of $lesssim 10^9$ g PBHs can be used to explore and discriminate different formation scenarios of spinning and non-spinning PBHs spanning orders of magnitude in mass-range, which is challenging to do otherwise.