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Time Reversal Symmetry for Classical, Nonrelativistic Quantum and Spin Systems in Presence of Magnetic Fields

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 Added by Davide Carbone
 Publication date 2021
  fields Physics
and research's language is English




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We extend to quantum mechanical systems results previously obtained for classical mechanical systems, concerning time reversibility in presence of a magnetic field. As in the classical case, results like the Onsager reciprocal relations are consequently obtained, without recourse to the Casimir modification. The quantum systems treated here are nonrelativistic, and are described by the Schr{o}dinger equation or the Pauli equation. In particular, we prove that the spin-field interaction does not break the time reversal invariance (TRI) of the dynamics, and that it does not require additional conditions for such a symmetry to hold, compared to the spinless cases.



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Time reversal invariance (TRI) of particles systems has many consequences, among~which the celebrated Onsager reciprocal relations, a milestone in Statistical Mechanics dating back to 1931. Because for a long time it was believed that (TRI) dos not hold in presence of a magnetic field, a modification of such relations was proposed by Casimir in 1945. Only in the last decade, the~strict traditional notion of reversibility that led to Casimirs work has been questioned. It was then found that other symmetries can be used, which allow the Onsager reciprocal relations to hold without modification. In this paper we advance this investigation for classical Hamiltonian systems, substantially increasing the number of symmetries that yield TRI in presence of a magnetic field. We~first deduce the most general form of a generalized time reversal operation on the phase space of such a system; secondly, we express sufficient conditions on the magnetic field which ensure TRI. Finally, we examine common examples from statistical mechanics and molecular dynamics. Our main result is that TRI holds in a much wider generality than previously believed, partially explaining why no experimental violation of Onsager relations has so far been reported.
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