A new thixotropic model is developed integrating the Papanastasiou-Bingham model with thixotropy equations to simulate the flow behaviour of Tremie Concrete in the Material Point Method framework. The effect of thixotropy on the rheological behaviour of fresh concrete is investigated by comparing field measurements with numerical simulations. The comparison yields new insights into a critical and often overlooked behaviour of concrete. A parametric study is performed to understand the effect of model parameters and rest-time on the shear stress response of fresh concrete. The Material Point Method with the Papanastasiou-Bingham model reproduces slump-flow measurements observed in the field. The novel model revealed a decline in concrete workability during the Slump-flow test after a period of rest due to thixotropy, which the physical version of the test fails to capture. This reduction in workability significantly affects the flow behaviour and the effective use of fresh concrete in construction operation.