We construct relative moduli spaces of semistable pairs on a family of projective Deligne-Mumford stacks. We define moduli stacks of stable orbifold Pandharipande-Thomas pairs on stacks of expanded degenerations and pairs, and then show they are separated and proper Deligne-Mumford stacks of finite type. As an application, we present the degeneration formula for the absolute and relative orbifold Pandharipande-Thomas invariants.