Subscribe to the gold package and get unlimited access to Shamra Academy
Register a new userExit dynamics from Morse potential under thermal fluctuations
78
0
0.0
(
0
)
Ask ChatGPT about the research
No Arabic abstract
We study the dynamics of a Brownian particle in Morse potential under thermal fluctuations, modeled by Gaussian white noise whose amplitude depends on absolute temperature. Dynamics of such a particle is investigated by numerically integrating the corresponding Langevin equation. From the mean first passage time (escape time), we study the dependence of Kramers rate on temperature and viscosity of the medium. An approximate expression for the reaction rate is found by solving differential equation for the mean first passage time. The expression shows a temperature dependent pre-factor for the Arrhenius equation. Our numerical simulations are in agreement with analytical approximations.
rate research
Read More
Large fluctuations have received considerable attention as they encode information on the fine-scale dynamics. Large deviation relations known as fluctuation theorems also capture crucial nonequilibrium thermodynamical properties. Here we report that, using the technique of uniformization, the thermodynamic large deviation functions of continuous-time Markov processes can be obtained from Markov chains evolving in discrete time. This formulation offers new theoretical and numerical approaches to explore large deviation properties. In particular, the time evolution of autonomous and non-autonomous processes can be expressed in terms of a single Poisson rate. In this way the uniformization procedure leads to a simple and efficient way to simulate stochastic trajectories that reproduce the exact fluxes statistics. We illustrate the formalism for the current fluctuations in a stochastic pump model.
We analyze the diffusive motion of kink solitons governed by the thermal sine-Gordon equation. We analytically calculate the correlation function of the position of the kink center as well as the diffusion coefficient, both up to second-order in temperature. We find that the kink behavior is very similar to that obtained in the overdamped limit: There is a quadratic dependence on temperature in the diffusion coefficient that comes from the interaction among the kink and phonons, and the average value of the wave function increases with $sqrt{t}$ due to the variance of the centers of individual realizations and not due to kink distortions. These analytical results are fully confirmed by numerical simulations.
In stationary nonequilibrium states coupling between hydrodynamic modes causes thermal fluctuations to become long ranged inducing nonequilibrium Casimir pressures. Here we consider nonequilibrium Casimir pressures induced in liquids by a velocity gradient. Specifically, we have obtained explicit expressions for the magnitude of the shear-induced pressure enhancements in a liquid layer between two horizontal plates that complete and correct results previously presented in the literature. In contrast to nonequilibrium Casimir pressures induced by a temperature or concentration gradient, we find that in shear nonequilibrium contributions from short-range fluctuations are no longer negligible. In addition, it is noted that currently available computer simulations of model fluids in shear observe effects from molecular correlations at nanoscales that have a different physical origin and do not probe shear-induced pressures resulting from coupling of long-wavelength hydrodynamic modes. Even more importantly, we find that in actual experimental conditions, shear-induced pressure enhancements are caused by viscous heating and not by thermal velocity fluctuations. Hence, isothermal computer simulations are irrelevant for the interpretation of experimental shear-induced pressure enhancements.
We consider the dynamics of fluctuations in the quantum asymmetric simple exclusion process (Q-ASEP) with periodic boundary conditions. The Q-ASEP describes a chain of spinless fermions with random hoppings that are induced by a Markovian environment. We show that fluctuations of the fermionic degrees of freedom obey evolution equations of Lindblad type, and derive the corresponding Lindbladians. We identify the underlying algebraic structure by mapping them to non-Hermitian spin chains and demonstrate that the operator space fragments into exponentially many (in system size) sectors that are invariant under time evolution. At the level of quadratic fluctuations we consider the Lindbladian on the sectors that determine the late time dynamics for the particular case of the quantum symmetric simple exclusion process (Q-SSEP). We show that the corresponding blocks in some cases correspond to known Yang-Baxter integrable models and investigate the level-spacing statistics in others. We carry out a detailed analysis of the steady states and slow modes that govern the late time behaviour and show that the dynamics of fluctuations of observables is described in terms of closed sets of coupled linear differential-difference equations. The behaviour of the solutions to these equations is essentially diffusive but with relevant deviations, that at sufficiently late times and large distances can be described in terms of a continuum scaling limit which we construct. We numerically check the validity of this scaling limit over a significant range of time and space scales. These results are then applied to the study of operator spreading at large scales, focusing on out-of-time ordered correlators and operator entanglement.
Numerical simulations and finite-size scaling analysis have been carried out to study the percolation behavior of straight rigid rods of length $k$ ($k$-mers) on two-dimensional square lattices. The $k$-mers, containing $k$ identical units (each one occupying a lattice site), were adsorbed at equilibrium on the lattice. The process was monitored by following the probability $R_{L,k}(theta)$ that a lattice composed of $L times L$ sites percolates at a concentration $theta$ of sites occupied by particles of size $k$. A nonmonotonic size dependence was observed for the percolation threshold, which decreases for small particles sizes, goes through a minimum, and finally asymptotically converges towards a definite value for large segments. This striking behavior has been interpreted as a consequence of the isotropic-nematic phase transition occurring in the system for large values of $k$. Finally, the universality class of the model was found to be the same as for the random percolation model.
Log in to be able to interact and post comments
comments
Fetching comments
Sign in to be able to follow your search criteria
