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Data suggest that most rocky exoplanets with orbital period $p$ $<$ 100 d (hot rocky exoplanets) formed as gas-rich sub-Neptunes that subsequently lost most of their envelopes, but whether these rocky exoplanets still have atmospheres is unknown. We identify a pathway by which 1-1.7 $R_{Earth}$ (1-10 $M_{Earth}$) rocky exoplanets with orbital periods of 10-100 days can acquire long-lived 10-2000 bar atmospheres that are H$_2$O-dominated, with mean molecular weight $>$10. These atmospheres form during the planets evolution from sub-Neptunes into rocky exoplanets. H$_2$O that is made by reduction of iron oxides in the silicate magma is highly soluble in the magma, forming a dissolved reservoir that is protected from loss so long as the H$_2$-dominated atmosphere persists. The large size of the dissolved reservoir buffers the H$_2$O atmosphere against loss after the H$_2$ has dispersed. Within our model, a long-lived, water-dominated atmosphere is a common outcome for efficient interaction between a nebula-derived atmosphere (peak atmosphere mass fraction 0.1-0.6 wt%) and oxidized magma ($>$5 wt% FeO), followed by atmospheric loss. This idea predicts that most rocky planets that have orbital periods of 10-100 days and that have radii within 0.1-0.2 $R_{Earth}$ of the lower edge of the radius valley still retain H$_2$O atmospheres. This prediction is imminently testable with JWST and has implications for the interpretation of data for transiting super-Earths.
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To ascertain whether magnetic dynamos operate in rocky exoplanets more massive or hotter than the Earth, we developed a parametric model of a differentiated rocky planet and its thermal evolution. Our model reproduces the established properties of Earths interior and magnetic field at the present time. When applied to Venus, assuming that planet lacks plate tectonics and has a dehydrated mantle with an elevated viscosity, the model shows that the dynamo shuts down or never operated. Our model predicts that at a fixed planet mass, dynamo history is sensitive to core size, but not to the initial inventory of long-lived, heat-producing radionuclides. It predicts that rocky planets larger than 2.5 Earth masses will not develop inner cores because the temperature-pressure slope of the iron solidus becomes flatter than that of the core adiabat. Instead, iron snow will condense near or at the top of these cores, and the net transfer of latent heat upwards will suppress convection and a dynamo. More massive planets can have anemic dynamos due to core cooling, but only if they have mobile lids (plate tectonics). The lifetime of these dynamos is shorter with increasing planet mass but longer with higher surface temperature. Massive Venus-like planets with stagnant lids and more viscous mantles will lack dynamos altogether. We identify two alternative sources of magnetic fields on rocky planets: eddy currents induced in the hot or molten upper layers of planets on very short period orbits, and dynamos in the ionic conducting layers of ocean planets with ~10% mass in an upper mantle of water (ice).
Mass and radius of planets transiting their host stars are provided by radial velocity and photometric observations. Structural models of solid exoplanet interiors are then constructed by using equations of state for the radial density distribution, which are compliant with the thermodynamics of the high-pressure limit. However, to some extent those structural models suffer from inherent degeneracy or non-uniqueness problems owing to a principal lack of knowledge of the internal differentiation state and/or the possible presence of an optically thick atmosphere. We here discuss the role of corresponding measurement errors, which adversely affect determinations of a planets mean density and bulk chemical composition. Precise measurements of planet radii will become increasingly important as key observational constraints for radial density models of individual solid low-mass exoplanets or super-Earths.
We investigate the impact on convective numerical simulations of thermo-compositional diabatic processes. We focus our study on simulations with a stabilizing temperature gradient and a destabilizing mean-molecular weight gradient. We aim to establish the possibility for a reduced temperature-gradient in such setups. A suite of 3D simulations were conducted using a numerical hydrodynamic code. We used as a simplified test case, a sample region of the secondary atmosphere of a hot rocky exoplanet within which the chemical transition CO+O $leftrightarrow$ CO$_{2}$ could occur. Newtonian cooling and a chemical source term was used to maintain a negative mean molecular weight gradient. Our results demonstrate that this setup can reduce the temperature gradient, a result which does not converge away with resolution or over time. We also show that the presence of the reduced temperature gradient is a function of the forcing timescales. The above transition leads to a bifurcation of the temperature profile when the chemical forcing is fast, reminiscent of the bifurcation seen in the boiling crisis for steam/liquid convection. With the reduced temperature gradient in these idealized setups, there exists the possibility for an analogy of the reddening (currently observed in the spectra of brown dwarfs) in the spectra of rocky exoplanet atmospheres. Detailed 1D modelling is needed, in order to characterize the equilibrium thermal and compositional gradients, the timescales, and the impact of a realistic equation of state, in order to assess if the regime identified here will develop in realistic situations. This possibility cannot, however, be excluded a priori. This prediction is new for terrestrial atmospheres and represents strong motivation for the use of diabatic models when analysing atmospheric spectra of rocky exoplanets that will be observed with e.g. the James Webb Space Telescope.
The runaway greenhouse represents the ultimate climate catastrophe for rocky, Earth-like worlds: when the incoming stellar flux cannot be balanced by radiation to space, the oceans evaporate and exacerbate heating, turning the planet into a hot wasteland with a steam atmosphere overlying a possibly molten magma surface. The equilibrium state beyond the runaway greenhouse instellation limit depends on the radiative properties of the atmosphere and its temperature structure. Here, we use 1-D radiative-convective models of steam atmospheres to explore the transition from the tropospheric radiation limit to the post-runaway climate state. To facilitate eventual simulations with 3-D global circulation models, a computationally efficient band-grey model is developed, which is capable of reproducing the key features of the more comprehensive calculations. We analyze two factors which determine the equilibrated surface temperature of post-runaway planets. The infrared cooling of the planet is strongly enhanced by the penetration of the dry adiabat into the optically thin upper regions of the atmosphere. In addition, thermal emission of both shortwave and near-IR fluxes from the hot lower atmospheric layers, which can radiate through window regions of the spectrum, is quantified. Astronomical surveys of rocky exoplanets in the runaway greenhouse state may discriminate these features using multi-wavelength observations.
Hydrogen cyanide (HCN) is a key feedstock molecule for the production of lifes building blocks. The formation of HCN in an N$_2$-rich atmospheres requires first that the triple bond between N$equiv$N be severed, and then that the atomic nitrogen find a carbon atom. These two tasks can be accomplished via photochemistry, lightning, impacts, or volcanism. The key requirements for producing appreciable amounts of HCN are the free availability of N$_2$ and a local carbon to oxygen ratio of C/O $geq 1$. We discuss the chemical mechanisms by which HCN can be formed and destroyed on rocky exoplanets with Earth-like N$_2$ content and surface water inventories, varying the oxidation state of the dominant carbon-containing atmospheric species. HCN is most readily produced in an atmosphere rich in methane (CH$_4$) or acetylene (C$_2$H$_2$), but can also be produced in significant amounts ($> 1$ ppm) within CO-dominated atmospheres. Methane is not necessary for the production of HCN. We show how destruction of HCN in a CO$_2$-rich atmosphere depends critically on the poorly-constrained energetic barrier for the reaction of HCN with atomic oxygen. We discuss the implications of our results for detecting photochemically produced HCN, for concentrating HCN on the planets surface, and its importance for prebiotic chemistry.
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