How the bulk of the Universes visible mass emerges and how it is manifest in the existence and properties of hadrons are profound questions that probe into the heart of strongly interacting matter. Paradoxically, the lightest pseudoscalar mesons appear to be the key to the further understanding of the emergent mass and structure mechanisms. These mesons, namely the pion and kaon, are the Nambu-Goldstone boson modes of QCD. Unravelling their partonic structure and the interplay between emergent and Higgs-boson mass mechanisms is a common goal of three interdependent approaches -- continuum QCD phenomenology, lattice-regularised QCD, and the global analysis of parton distributions -- linked to experimental measurements of hadron structure. Experimentally, the foreseen electron-ion collider will enable a revolution in our ability to study pion and kaon structure, accessed by scattering from the meson cloud of the proton through the Sullivan process. With the goal of enabling a suite of measurements that can address these questions, we examine key reactions to identify the critical detector system requirements needed to map tagged pion and kaon cross sections over a wide range of kinematics. The excellent prospects for extracting pion structure function and form factor data are shown, and similar prospects for kaon structure are discussed in the context of a worldwide programme. Successful completion of the programme outlined herein will deliver deep, far-reaching insights into the emergence of pions and kaons, their properties, and their role as QCDs Goldstone boson modes.
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