We present measurements of $f_h$, the ratio of the aligned components of the projected halo and galaxy ellipticities, for a sample of central galaxies using weak gravitational lensing data from the Kilo-Degree Survey (KiDS). Using a lens galaxy shape estimation that is more sensitive to outer galaxy regions, we find $f_{rm h}=0.50pm0.20$ for our full sample and $f_{rm h}=0.55pm0.19$ for an intrinsically red (and therefore higher stellar-mass) sub-sample, rejecting the hypothesis of round halos and/or galaxies being un-aligned with their parent halo at $2.5sigma$ and $2.9sigma$, respectively. We quantify the 93.4% purity of our central galaxy sample using numerical simulations and overlapping spectroscopy from the Galaxy and Mass Assembly survey. This purity ensures that the interpretation of our measurements is not complicated by the presence of a significant fraction of satellite galaxies. Restricting our central galaxy ellipticity measurement to the inner isophotes, we find $f_{rm h}=0.34pm0.17$ for our red sub-sample, suggesting that the outer galaxy regions are more aligned with their dark matter halos compared to the inner regions. Our results are in agreement with previous studies and suggest that lower mass halos are rounder and/or less aligned with their host galaxy than samples of more massive galaxies, studied in galaxy groups and clusters.