We present the discovery of CWISE J203546.35-493611.0, a peculiar M8 companion to the M4.5 star APMPM J2036-4936 discovered through the citizen science project Backyard Worlds: Planet 9. Given CWISE J203546.35-493611.0s proper motion ($mu_{alpha}$, $mu_{delta}$) = ($-$126$pm$22, $-$478$pm$23) and angular separation of 34.2$$ from APMPM 2036-4936, we calculate a chance alignment probability of $1.15 times 10^{-6}$. Both stars in this system appear to be underluminous, and the spectrum obtained for CWISE J203546.35-493611.0 shows a triangular H band. Further study of this system is warranted to understand these peculiarities.
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