Scalar fields coupled to the Gauss-Bonnet invariant can undergo a tachyonic instability, leading to spontaneous scalarization of black holes. Studies of this effect have so far been restricted to single black hole spacetimes. We present the first results on dynamical scalarization in head-on collisions and quasicircular inspirals of black hole binaries with numerical relativity simulations. We show that black hole binaries can either form a scalarized remnant or dynamically descalarize by shedding off its initial scalar hair. The observational implications of these findings are discussed.
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