Urbanization plays a crucial role in the economic development of every country. The mutual relationship between the urbanization of any country and its economic productive structure is far from being understood. We analyzed the historical evolution of product exports for all countries using the World Trade Web (WTW) with respect to patterns of urbanization from 1995-2010. Using the evolving framework of economic complexity, we reveal that a countrys economic development in terms of its production and export of goods, is interwoven with the urbanization process during the early stages of its economic development and growth. Meanwhile in urbanized countries, the reciprocal relation between economic growth and urbanization fades away with respect to its later stages, becoming negligible for countries highly dependent on the export of resources where urbanization is not linked to any structural economic transformation.
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