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Register a new userElectron-phonon coupling and superconductivity in the doped topological-crystalline insulator (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_x$Te
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We present a neutron scattering study of phonons in single crystals of (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_x$Te with $x=0$ (metallic, but nonsuperconducting) and $x=0.2$ (nonmetallic normal state, but superconducting). We map the phonon dispersions (more completely for $x=0$) and find general consistency with theoretical calculations, except for the transverse and longitudinal optical (TO and LO) modes at the Brillouin zone center. At low temperature, both modes are strongly damped but sit at a finite energy ($sim4$ meV in both samples), shifting to higher energy at room temperature. These modes are soft due to a proximate structural instability driven by the sensitivity of Pb-Te and Sn-Te $p$-orbital hybridization to off-center displacements of the metal atoms. The impact of the soft optical modes on the low-energy acoustic modes is inferred from the low thermal conductivity, especially at low temperature. Given that the strongest electron-phonon coupling is predicted for the LO mode, which should be similar for both studied compositions, it is intriguing that only the In-doped crystal is superconducting. In addition, we observe elastic diffuse (Huang) scattering that is qualitatively explained by the difference in Pb-Te and Sn-Te bond lengths within the lattice of randomly distributed Pb and Sn sites. We also confirm the presence of anomalous diffuse low-energy atomic vibrations that we speculatively attribute to local fluctuations of individual Pb atoms between off-center sites.
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Indium substitution turns the topological crystalline insulator (TCI) Pb$_{0.5}$Sn$_{0.5}$Te into a possible topological superconductor. To investigate the effect of the indium concentration on the crystal structure and superconducting properties of (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_{x}$Te, we have grown high-quality single crystals using a modified floating-zone method, and have performed systematic studies for indium content in the range $0leq xleq 0.35$. We find that the single crystals retain the rock salt structure up to the solubility limit of indium ($xsim0.30$). Experimental dependences of the superconducting transition temperature ($T_c$) and the upper critical magnetic field ($H_{c2}$) on the indium content $x$ have been measured. The maximum $T_c$ is determined to be 4.7 K at $x=0.30$, with $mu_0H_{c2}(T=0)approx 5$ T.
We present inelastic neutron scattering results of phonons in (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_x$Te powders, with $x=0$ and 0.3. The $x=0$ sample is a topological crystalline insulator, and the $x=0.3$ sample is a superconductor with a bulk superconducting transition temperature $T_c$ of 4.7 K. In both samples, we observe unexpected van Hove singularities in the phonon density of states at energies of 1--2.5 meV, suggestive of local modes. On cooling the superconducting sample through $T_c$, there is an enhancement of these features for energies below twice the superconducting-gap energy. We further note that the superconductivity in (Pb$_{0.5}$Sn$_{0.5}$)$_{1-x}$In$_x$Te occurs in samples with normal-state resistivities of order 10 m$Omega$~cm, indicative of bad-metal behavior. Calculations based on density functional theory suggest that the superconductivity is easily explainable in terms of electron-phonon coupling; however, they completely miss the low-frequency modes and do not explain the large resistivity. While the bulk superconducting state of (Pb$_{0.5}$Sn$_{0.5}$)$_{0.7}$In$_{0.3}$Te appears to be driven by phonons, a proper understanding will require ideas beyond simple BCS theory.
Pb$_{1-x}$Sn$_x$Te has been shown to be an interesting tunable topological crystalline insulator system. We present a magneto-terahertz spectroscopic study of thin films of Pb$_{0.5}$Sn$_{0.5}$Te. The complex Faraday rotation angle and optical conductivity in the circular basis are extracted without any additional assumptions. Our quantitative measures of the THz response allow us to show that the sample studied contains two types of bulk carriers. One is $p$-type and originates in 3D Dirac bands. The other is $n$-type and appears to be from more conventional 3D bands. These two types of carriers display different cyclotron resonance dispersions. Through simulating the cyclotron resonance of hole carriers, we can determine the Fermi energy and Fermi velocity. Furthermore, the scattering rates of $p$-type and $n$-type carriers were found to show opposite field dependences, which can be attributed to their different Landau level broadening behaviors under magnetic field. Our work provides a new way to isolate real topological signatures of bulk states in Dirac and Weyl semimetals.
The temperature dependence of the London penetration depth $Deltalambda(T)$ in the superconducting doped topological crystalline insulator Sn$_{1-x}$In$_x$Te was measured down to 450 mK for two different doping levels, x $approx$ 0.45 (optimally doped) and x $approx$ 0.10 (underdoped), bookending the range of cubic phase in the compound. The results indicate no deviation from fully gapped BCS-like behavior, eliminating several candidate unconventional gap structures. Critical field values below 1 K and other superconducting parameters are also presented. The introduction of disorder by repeated particle irradiation with 5 MeV protons does not enhance $T_c$, indicating that ferroelectric interactions do not compete with superconductivity.
The ratio of the Zeeman splitting to the cyclotron energy ($M=Delta E_Z / hbar omega_c$), which characterizes the relative strength of the spin-orbit interaction in crystals, is examined for the narrow gap IV-VI semiconductors PbTe, SnTe, and their alloy Pb$_{1-x}$Sn$_x$Te on the basis of the multiband $kcdot p$ theory. The inverse mass $alpha$, the g-factor $g$, and $M$ are calculated numerically by employing the relativistic empirical tight-binding band calculation. On the other hand, a simple but exact formula of $M$ is obtained for the six-band model based on the group theoretical analysis. It is shown that $M<1$ for PbTe and $M>1$ for SnTe, which are interpreted in terms of the relevance of the interband couplings due to the crystalline spin-orbit interaction. It is clarified both analytically and numerically that $M=1$ just at the band inversion point, where the transition from trivial to nontrivial topological crystalline insulator occurs. By using this property, one can detect the transition point only with the bulk measurements. It is also proposed that $M$ is useful to evaluate quantitatively a degree of the Dirac electrons in solids.
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