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Register a new userCesium $nD_{J}$+$6S_{1/2}$ Rydberg molecules and their permanent electric dipole moments
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Cs$_2$ Rydberg-ground molecules consisting of a Rydberg, $nD_{J}$ (33 $leq$ $n$ $leq$ 39), and a ground state atom, 6$S_{1/2} (F=$3 or 4$)$, are investigated by photo-association spectroscopy in a cold atomic gas. We observe vibrational spectra that correspond to triplet $^TSigma$ and mixed $^{S,T}Sigma$ molecular states. We establish scaling laws for the energies of the lowest vibrational states vs principal quantum number and obtain zero-energy singlet and triplet $s$-wave scattering lengths from experimental data and a Fermi model. Line broadening in electric fields reveals the permanent molecular electric-dipole moments; measured values agree well with calculations. We discuss the negative polarity of the dipole moments, which differs from previously reported cases.
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Water clusters embedding a nitric acid molecule HNO3(H2O)_{n=1-10} are investigated via electrostatic deflection of a molecular beam. We observe large paraelectric susceptibilities that greatly exceed the electronic polarizability, revealing the contribution of permanent dipole moments. The moments derived from the data are also significantly higher than those of pure water clusters. An enhancement in the susceptibility for n=5,6 and a rise in cluster abundances setting in at n=6 suggest that dissociation of the solvated acid molecule into ions takes place in this size range.
A nonzero electric dipole moment (EDM) of the neutron, proton, deuteron or helion, in fact, of any finite system necessarily involves the breaking of a symmetry, either by the presence of external fields (i.e. electric fields leading to the case of induced EDMs) or explicitly by the breaking of the discrete parity and time-reflection symmetries in the case of permanent EDMs. We discuss two theorems describing these phenomena and report about the cosmological motivation for an existence of CP breaking beyond what is generated by the Kobayashi-Maskawa mechanism in the Standard Model and what this might imply for the permanent electric dipole moments of the nucleon and light nuclei by estimating a window of opportunity for physics beyond what is currently known. Recent - and in the case of the deuteron even unpublished - results for the relevant matrix elements of nuclear EDM operators are presented and the relevance for disentangling underlying New Physics sources are discussed.
We first give a short review of the ``local-current approximation (LCA), derived from a general variation principle, which serves as a semiclassical description of strongly collective excitations in finite fermion systems starting from their quantum-mechanical mean-field ground state. We illustrate it for the example of coupled translational and compressional dipole excitations in metal clusters. We then discuss collective electronic dipole excitations in C$_{60}$ molecules (Buckminster fullerenes). We show that the coupling of the pure translational mode (``surface plasmon) with compressional volume modes in the semiclasscial LCA yields semi-quantitative agreement with microscopic time-dependent density functional (TDLDA) calculations, while both theories yield qualitative agreement with the recent experimental observation of a ``volume plasmon.
The induced polarization of a beam of polar clusters or molecules passing through an electric or magnetic field region differs from the textbook Langevin-Debye susceptibility. This distinction, which is important for the interpretation of deflection and focusing experiments, arises because instead of acquiring thermal equilibrium in the field region, the beam ensemble typically enters the field adiabatically, i.e., with a previously fixed distribution of rotational states. We discuss the orientation of rigid symmetric-top systems with a body-fixed electric or magnetic dipole moment. The analytical expression for their adiabatic-entry orientation is elucidated and compared with exact numerical results for a range of parameters. The differences between the polarization of thermodynamic and adiabatic-entry ensembles, of prolate and oblate tops, and of symmetric-top and linear rotators are illustrated and identified.
We create fermionic dipolar $^{23}$Na$^6$Li molecules in their triplet ground state from an ultracold mixture of $^{23}$Na and $^6$Li. Using magneto-association across a narrow Feshbach resonance followed by a two-photon STIRAP transfer to the triplet ground state, we produce $3,{times},10^4$ ground state molecules in a spin-polarized state. We observe a lifetime of $4.6,text{s}$ in an isolated molecular sample, approaching the $p$-wave universal rate limit. Electron spin resonance spectroscopy of the triplet state was used to determine the hyperfine structure of this previously unobserved molecular state.
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