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Register a new userChemically-distinct regions within Venus atmosphere revealed by MESSENGER-measured N2 concentrations
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A defining characteristic of the planet Venus is its thick, CO2-dominated atmosphere. Despite over fifty years of robotic exploration, including thirteen successful atmosphere probes and landers, our knowledge of N2, the second-most-abundant compound in the atmosphere, is highly uncertain (von Zahn et al., 1983). We report the first measurement of the nitrogen content of Venus atmosphere at altitudes between 60 and 100 km. Our result, 5.0 +/- 0.4 v% N2, is significantly higher than the value of 3.5 v% N2 reported for the lower atmosphere (<50 km altitude). We conclude that Venus atmosphere contains two chemically-distinct regions, contrasting sharply with the expectation that it should be uniform across these altitude due to turbulent mixing (e.g. Oyama et al., 1980). That the lower-mass component is more concentrated at high altitudes suggests that the chemical profile of the atmosphere above 50-km altitude reflects mass segregation of CO2 and N2. A similar boundary between well-mixed and mass-segregated materials exists for Earth, however it is located at a substantially higher altitude of ~100 km. That Venus upper and lower atmosphere are not in chemical equilibrium complicates efforts to use remote sensing measurements to infer the properties of the lower atmosphere and surface, a lesson that also applied to the growing field of exoplanet astronomy. The observation of periodic increases in SO2 concentrations in Venus upper atmosphere, which has been cited as evidence for active volcanic eruptions at the surface (Esposito et al., 1984), may instead be attributable to atmosphere processes that periodically inject SO2 from the lower atmosphere into the upper atmosphere.
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The detection of phosphine (PH3) in the atmosphere of Venus has been recently reported based on millimeter-wave radio observations (Greaves et al. 2020), and its re-analyses (Greaves et al. 2021a/b). In this Matters Arising we perform an independent reanalysis, identifying several issues in the interpretation of the spectroscopic data. As a result, we determine sensitive upper-limits for PH3 in Venus atmosphere (>75 km, above the cloud decks) that are discrepant with the findings in G2020 and G2021a/b. The measurements target the fundamental first rotational transition of PH3 (J=1-0) at 266.944513 GHz, which was observed with the James Clerk Maxwell Telescope (JCMT) in June 2017 and with the Atacama Large Millimeter/submillimeter Array (ALMA) in March 2019. This lines center is near the SO2 (J=309,21-318,24) transition at 266.943329 GHz (only 1.3 km/s away from the PH3 line) which represents a potential source of contamination. The JCMT and ALMA data, as presented in G2020, are at spectral resolutions comparable to the frequency separation of the two lines. Moreover, the spectral features identified are several km/s in width, and therefore do not permit distinct spectroscopic separation of the candidate spectral lines of PH3 and SO2. We present the radiative transfer modelling we have performed and then discuss the ALMA and JCMT analyses in turn.
One of the most intriguing, long-standing questions regarding Venus atmosphere is the origin and distribution of the unknown UV-absorber, responsible for the absorption band detected at the near-UV and blue range of Venus spectrum. In this work, we use data collected by MASCS spectrograph on board the MESSENGER mission during its second Venus flyby in June 2007 to address this issue. Spectra range from 0.3 {mu}m to 1.5 {mu}m including some gaseous H2O and CO2 bands, as well as part of the SO2 absorption band and the core of the UV absorption. We used the NEMESIS radiative transfer code and retrieval suite to investigate the vertical distribution of particles in the Equatorial atmosphere and to retrieve the imaginary refractive indices of the UV-absorber, assumed to be well mixed with Venus small mode-1 particles. The results show an homogeneous Equatorial atmosphere, with cloud tops (height for unity optical depth) at 75+/-2 km above surface. The UV absorption is found to be centered at 0.34+/-0.03 {mu}m with a full width half maximum of 0.14+/-0.01 {mu}m. Our values are compared with previous candidates for the UV aerosol absorber, among which disulfur oxide (S2O) and dioxide disulfur (S2O2) provide the best agreement with our results.
The Venusian atmosphere is in a state of superrotation where prevailing westward winds move much faster than the planets rotation. Venus is covered with thick clouds that extend from about 45 to 70 km altitude, but thermal radiation emitted from the lower atmosphere and the surface on the planets nightside escapes to space at narrow spectral windows of the near-infrared. The radiation can be used to estimate winds by tracking the silhouettes of clouds in the lower and middle cloud regions below about 57 km in altitude. Estimates of wind speeds have ranged from 50 to 70 m/s at low to mid-latitudes, either nearly constant across latitudes or with winds peaking at mid-latitudes. Here we report the detection of winds at low latitude exceeding 80 m/s using IR2 camera images from the Akatsuki orbiter taken during July and August 2016. The angular speed around the planetary rotation axis peaks near the equator, which we suggest is consistent with an equatorial jet, a feature that has not been observed previously in the Venusian atmosphere. The mechanism producing the jet remains unclear. Our observations reveal variability in the zonal flow in the lower and middle cloud region that may provide clues to the dynamics of Venuss atmospheric superrotation.
Venus shares many similarities with the Earth, but concomitantly, some of its features are extremely original. This is especially true for its atmosphere, where high pressures and temperatures are found at the ground level. In these conditions, carbon dioxide, the main component of Venus atmosphere, is a supercritical fluid. The analysis of VeGa-2 probe data has revealed the high instability of the region located in the last few kilometers above the ground level. Recent works have suggested an explanation based on the existence of a vertical gradient of molecular nitrogen abundances, around 5 ppm per meter. Our goal was then to identify which physical processes could lead to the establishment of this intriguing nitrogen gradient, in the deep atmosphere of Venus. Using an appropriate equation of state for the binary mixture CO2-N2 under supercritical conditions, and also molecular dynamics simulations, we have investigated the separation processes of N2 and CO2 in the Venusian context. Our results show that molecular diffusion is strongly inefficient, and potential phase separation is an unlikely mechanism. We have compared the quantity of CO2 required to form the proposed gradient with what could be released by a diffuse degassing from a low volcanic activity. The needed fluxes of CO2 are not so different from what can be measured over some terrestrial volcanic systems, suggesting a similar effect at work on Venus.
The atmosphere of a transiting planet shields the stellar radiation providing us with a powerful method to estimate its size and density. In particular, because of their high ionization energy, atoms with high atomic number (Z) absorb short-wavelength radiation in the upper atmosphere, undetectable with observations in visible light. One implication is that the planet should appear larger during a primary transit observed in high energy bands than in the optical band. The last Venus transit in 2012 offered a unique opportunity to study this effect. The transit has been monitored by solar space observations from Hinode and Solar Dynamics Observatory (SDO). We measure the radius of Venus during the transit in three different bands with subpixel accuracy: optical (4500A), UV (1600A, 1700A), Extreme UltraViolet (EUV, 171-335A) and soft X-rays (about 10A). We find that, while the Venus optical radius is about 80 km larger than the solid body radius (the expected opacity mainly due to clouds and haze), the radius increases further by more than 70 km in the EUV and soft X-rays. These measurements mark the densest ion layers of Venus ionosphere, providing information about the column density of CO2 and CO. They are useful for planning missions in situ to estimate the dynamical pressure from the environment, and can be employed as a benchmark case for observations with future missions, such as the ESA Athena, which will be sensitive enough to detect transits of exoplanets in high-energy bands.
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