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We present an observational study of the sulfur (S)-bearing species towards Orion KL at 1.3 mm by combining ALMA and IRAM-30,m single-dish data. At a linear resolution of $sim$800 au and a velocity resolution of 1 $mathrm{km, s^{-1}, }$, we have identified 79 molecular lines from 6 S-bearing species. In these S-bearing species, we found a clear dichotomy between carbon-sulfur compounds and carbon-free S-bearing species in various characteristics, e.g., line profiles, spatial morphology, and molecular abundances with respect to $rm H_2$. Lines from the carbon-sulfur compounds (i.e., OCS, $^{13}$CS, H$_2$CS) exhibit spatial distributions concentrated around the continuum peaks and extended to the south ridge. The full width at half maximum (FWHM) linewidth of these molecular lines is in the range of 2 $sim$ 11 $mathrm{km, s^{-1}, }$. The molecular abundances of OCS and H$_2$CS decrease slightly from the cold ($sim$68 K) to the hot ($sim$176 K) regions. In contrast, lines from the carbon-free S-bearing species (i.e., SO$_2$, $^{34}$SO, H$_2$S) are spatially more extended to the northeast of mm4, exhibiting broader FWHM linewidths (15 $sim$ 26 $mathrm{km, s^{-1}, }$). The molecular abundances of carbon-free S-bearing species increase by over an order of magnitude as the temperature increase from 50 K to 100 K. In particular, $mathrm{^{34}SO/^{34}SO_2}$ and $mathrm{OCS/SO_2}$ are enhanced from the warmer regions ($>$100 K) to the colder regions ($sim$50 K). Such enhancements are consistent with the transformation of SO$_2$ at warmer regions and the influence of shocks.
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We present a comprehensive study of the deuterated molecules detected in the fullband HIFI survey of the Orion KL region. Ammonia, formaldehyde, and methanol and their singly deuterated isotopologues are each detected through numerous transitions in this survey with a wide range in optical depths and excitation conditions. In conjunction with a recent study of the abundance of HDO and H$_2$O in Orion KL, this study yields the best constraints on deuterium fractionation in an interstellar molecular cloud to date. As previous studies have found, both the Hot Core and Compact Ridge regions within Orion KL contain significant abundances of deuterated molecules, suggesting an origin in cold grain mantles. In the Hot Core, we find that ammonia is roughly a factor of 2 more fractionated than water. In the Compact Ridge, meanwhile, we find similar deuterium fractionation in water, formaldehyde, and methanol, with D/H ratios of (2---8) $times$ $10^{-3}$. The [CH$_2$DOH]/[CH$_3$OD] ratio in the Compact Ridge is found to be $1.2 pm 0.3$. The Hot Core generally has lower deuterium fractionation than the Compact Ridge, suggesting a slightly warmer origin, or a greater contribution from warm gas phase chemistry.
Since the start of ALMA observatory operation, new and important chemistry of infrared cold core was revealed. Molecular transitions at millimeter range are being used to identify and to characterize these sources. We have investigated the 231 GHz ALMA archive observations of the infrared dark cloud region C9, focusing on the brighter source that we called as IRDC-C9 Main. We report the existence of two sub-structures on the continuum map of this source: a compact bright spot with high chemistry diversity that we labelled as core, and a weaker and extended one, that we labelled as tail. In the core, we have identified lines of the molecules OCS(19-18), $^{13}$CS(5-4) and CH$_{3}$CH$_{2}$CN, several lines of CH$_{3}$CHO and the k-ladder emission of $^{13}$CH$_{3}$CN.We report two different temperature regions: while the rotation diagram of CH$_{3}$CHO indicates a temperature of 25 K, the rotation diagram of $^{13}$CH$_{3}$CN indicates a warmer phase at temperature of $sim450$K. In the tail, only the OCS(19-18) and $^{13}$CS(5-4) lines were detected. We used the $Nautilus$ and the textsc{Radex} codes to estimate the column densities and the abundances. The existence of hot gas in the core of IRDC-C9 Main suggests the presence of a protostar, which is not present in the tail.
We have observed the Class I protostellar source Elias 29 with Atacama Large Millimeter/submillimeter Array (ALMA). We have detected CS, SO, $^{34}$SO, SO$_2$, and SiO line emissions in a compact component concentrated near the protostar and a ridge component separated from the protostar by 4arcsec ($sim 500$ au). The former component is found to be abundant in SO and SO$_2$ but deficient in CS. The abundance ratio SO/CS is as high as $3^{+13}_{-2} times 10^2$ at the protostar, which is even higher than that in the outflow-shocked region of L1157 B1. However, organic molecules (HCOOCH$_3$, CH$_3$OCH$_3$, CCH, and c-C$_3$H$_2$) are deficient in Elias 29. We attribute the deficiency in organic molecules and richness in SO and SO$_2$ to the evolved nature of the source or the relatively high dust temperature (protectraisebox{-0.7ex}{$:stackrel{textstyle >}{sim}:$} 20 K) in the parent cloud of Elias 29. The SO and SO$_2$ emissions trace rotation around the protostar. Assuming a highly inclined configuration ($i geq 65$degr; 0degr for a face-on configuration) and Keplerian motion for simplicity, the protostellar mass is estimated to be (0.8 -- 1.0) Msun. The $^{34}$SO and SO$_2$ emissions are asymmetric in their spectra; the blue-shifted components are weaker than the red-shifted ones. Although this may be attributed to the asymmetric molecular distribution, other possibilities are also discussed.
Phosphorus is a key ingredient in terrestrial biochemistry, but is rarely observed in the molecular ISM and therefore little is known about how it is inherited during the star and planet formation sequence. We present observations of the phosphorus-bearing molecules PO and PN towards the Class I low-mass protostar B1-a using the IRAM 30m telescope, representing the second detection of phosphorus carriers in a Solar-type star forming region. The P/H abundance contained in PO and PN is ~10$^{-10}$-10$^{-9}$ depending on the assumed source size, accounting for just 0.05-0.5% of the solar phosphorus abundance and implying significant sequestration of phosphorus in refractory material. Based on a comparison of the PO and PN line profiles with the shock tracers SiO, SO$_2$, and CH$_3$OH, the phosphorus molecule emission seems to originate from shocked gas and is likely associated with a protostellar outflow. We find a PO/PN column density ratio of ~1-3, which is consistent with the values measured in the shocked outflow of the low-mass protostar L1157, the massive star-forming regions W51 and W3(OH), and the galactic center GMC G+0.693-0.03. This narrow range of PO/PN ratios across sources with a range of environmental conditions is surprising, and likely encodes information on how phosphorus carriers are stored in grain mantles.
The infrared source known as Orion n was detected in 1980 with observations made with the 3.8-m United Kingdom Infrared Telescope. About two decades later, sensitive observations made with the Very Large Array revealed the presence of a mJy double radio source apparently coincident in position with the infrared source n. The radio source was assumed to be the counterpart of the infrared source. However, over the years it has been concluded that the radio source shows large proper motions to the south while the infrared source n is stationary. Here we reanalyze the proper motions of the radio source adding both older and newer VLA observations than previously used. We confirm the proper motions of the radio source that at present no longer coincides positionally with the infrared source. The solution to this problem is, most probably, that the infrared source n and the radio source are not the same object: the infrared source is a stationary object in the region while the radio counterpart is moving as a result of the explosion that took place in this region some 500 years ago and that expelled large amounts of molecular gas as well as several compact sources. Considering the paper where it was first reported, we refer to this double radio source as Orion MR. In addition, we use these new observations to fully confirm the large proper motions of the sources IRc23 and Zapata 11. Together with sources BN, I, Orion MR, and x, there are at least six compact sources that recede from a point in common in Orion BN/KL. However, IRc23 is peculiar in that its ejection age appears to be only $sim$300 years. The relatively large number of sources rules out as a possible mechanism the classic three-body scenario since then only two escaping bodies are expected: a tight binary plus the third star involved in the encounter.
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