Highly directional and lossless surface wave has significant potential applications in the two-dimensional photonic circuits and devices. Here we experimentally demonstrate a selective Dyakonov surface wave coupling at the interface between a transparent polycarbonate material and nematic liquid crystal 5CB. By controlling the anisotropy of the nematic liquid crystal with an applied magnetic field, a single ray at a certain incident angle from a diverged incident beam can be selectively coupled into surface wave. The implementation of this property may lead to a new generation of on-chip integrated optics and two-dimensional photonic devices.
Dyakonov surface wave existing at the interface with anisotropy offers a promising way of guiding light in two-dimension with almost no loss. However, predicted decades ago, the experimental demonstration of the Dyakonov surface wave seems always challenging for the weak anisotropic indices from the natural materials. Here we experimentally demonstrated a Dyakonov surface wave mode propagating in a hyperbolic metasurface at the visible frequency. Dyakonov surface waves at the two surfaces of the metasurface can be supported simultaneously by the hyperbolic anisotropy and form a Dyakonov typed mode with low loss and a large allowed angle band. A detailed theoretical analysis and numerical simulations prove that the electric field of such a surface wave mode shows transverse spin, whose direction is determined by the orientations of the hyperbolic anisotropy and surface normal, based on which we experimentally observed the photonic spin Hall effect of the surface wave mode in our metasurface.
In order to ascertain conditions for surface-wave propagation guided by the planar interface of an isotropic dielectric material and a sculptured nematic thin film (SNTF) with periodic nonhomogeneity, we formulated a boundary-value problem, obtained a dispersion equation therefrom, and numerically solved it. The surface waves obtained are Dyakonov-Tamm waves. The angular domain formed by the directions of propagation of the Dyakonov--Tamm waves can be very wide (even as wide as to allow propagation in every direction in the interface plane), because of the periodic nonhomogeneity of the SNTF. A search for Dyakonov-Tamm waves is, at the present time, the most promising route to take for experimental verification of surface-wave propagation guided by the interface of two dielectric materials, at least one of which is anisotropic. That would also assist in realizing the potential of such surface waves for optical sensing of various types of analytes infiltrating one or both of the two dielectric materials.
Novel liquid crystalline (LC) compositions are suggested and studied as elements of LC-nose. This allows for optical detection of several volatile organic compounds (VOCs). Ethanol, toluene, pyridine and acetic acid were detected by means of colorimetric and spectroscopic techniques during their diffusion inside chiral elements of LC-nose. Selectivity to different VOCs is enhanced by means of components of liquid crystal matrix with different viscosity, affinities to the solvents, and abilities to form hydrogen bonding.
We propose a simple scaling theory describing the variation of the mean first passage time (MFPT) $tau(N,M)$ of a regular block copolymer of chain length $N$ and block size $M$ which is dragged through a selective liquid-liquid interface by an external field $B$. The theory predicts a non-Arrhenian $tau$ vs. $B$ relationship which depends strongly on the size of the blocks, $M$, and rather weakly on the total polymer length, $N$. The overall behavior is strongly influenced by the degree of selectivity between the two solvents $chi$. The variation of $tau(N,M)$ with $N$ and $M$ in the regimes of weak and strong selectivity of the interface is also studied by means of computer simulations using a dynamic Monte Carlo coarse-grained model. Good qualitative agreement with theoretical predictions is found. The MFPT distribution is found to be well described by a $Gamma$ - distribution. Transition dynamics of ring- and telechelic polymers is also examined and compared to that of the linear chains. The strong sensitivity of the ``capture time $tau(N,M)$ with respect to block length $M$ suggests a possible application as a new type of chromatography designed to separate and purify complex mixtures with different block sizes of the individual macromolecules.
Studying basic physical effects sustained in metamaterials characterized by specific constitutive relation is a research topic with a long standing tradition. Besides intellectual curiosity, it derives its importance from the ability to predict observable phenomena that are, if found with an actual metamaterial, a clear indication on its properties. Here, we consider a nonlocal (strong spatial dispersion), lossy, and isotropic metamaterial and study the impact of the nonlocality on the dispersion relation of surface plasmon polaritons sustained at an interface between vacuum and such metamaterial. For that, Fresnel coefficients are calculated and appropriate surface plasmon polaritons existence conditions are being proposed. Predictions regarding the experimentally observable reflection from a frustrated internal reflection geometry are being made. A different behavior for TE and TM polarization is observed. Our work unlocks novel opportunities to seek for traces of the nonlocality in experiments made with nowadays metamaterials.