No Arabic abstract
The only alkali metal known to be superconducting at ambient pressure is Li at 0.4 mK. Under 30 GPa pressure textit{T}$_{c}$ for Li rises to 14 K. In addition, nearly 50 years ago the heavy alkali metal Cs was reported to become superconducting near 1.3 K at 12 GPa. In the present experiment the superconductivity of Cs under pressure is confirmed. In addition, strong evidence is presented in electrical resistivity measurements that neighboring Rb also becomes superconducting near 2 K at 55 GPa as it enters the textit{oC}16 phase, as for Cs, where textit{T}$_{c}$ decreases under the application of pressure. It would seem likely that under the right temperature/pressure conditions all alkali metals, including metallic hydrogen, will join the ranks of the superconducting elements. With the addition of Rb, 55 of the 92 naturally occurring elements are superconducting at ambient or high pressure.
We present electrical resistance measurements of elemental yttrium on bulk and film samples, and both exhibit superconductivity at very high pressures. We show that the pressure dependence of the superconducting transition temperature above 100 GPa is in good agreement with the predicted Fddd phase by Chen et al. [Phys. Rev. lett. 109, 157004 (2012)]. This result together with a new Rietveld refinement made on X-ray data at 123 GPa from Samudrala et al. [J. Phys. Condens. Matter 24, 362201 (2012)] offer strong evidence that the atomic structure of yttrium above 100 GPa is orthorhombic Fddd. Furthermore, our process of evaporating yttrium film directly on a diamond anvil is expected to be a valuable asset for future synthesis of new superhydride superconductors.
Ytterbium (Yb) metal is divalent and nonmagnetic but would be expected under sufficient pressure to become trivalent and magnetic. We have carried out electrical resistivity and ac magnetic susceptibility measurements on Yb to pressures as high as 179 GPa over the temperature range 1.4 - 295 K. No evidence for magnetic order is observed. However, above 86 GPa Yb is found to become superconducting near 1.4 K with a transition temperature that increases monotonically with pressure to approximately 4.6 K at 179 GPa. Yb thus becomes the 54th known elemental superconductor.
We have constructed a pressure$-$temperature ($P-T$) phase diagram of $P$-induced superconductivity in EuFe$_2$As$_2$ single crystals, via resistivity ($rho$) measurements up to 3.2 GPa. As hydrostatic pressure is applied, an antiferromagnetic (AF) transition attributed to the FeAs layers at $T_mathrm{0}$ shifts to lower temperatures, and the corresponding resistive anomaly becomes undetectable for $P$ $ge$ 2.5 GPa. This suggests that the critical pressure $P_mathrm{c}$ where $T_mathrm{0}$ becomes zero is about 2.5 GPa. We have found that the AF order of the Eu$^{2+}$ moments survives up to 3.2 GPa without significant changes in the AF ordering temperature $T_mathrm{N}$. The superconducting (SC) ground state with a sharp transition to zero resistivity at $T_mathrm{c}$ $sim$ 30 K, indicative of bulk superconductivity, emerges in a pressure range from $P_mathrm{c}$ $sim$ 2.5 GPa to $sim$ 3.0 GPa. At pressures close to but outside the SC phase, the $rho(T)$ curve shows a partial SC transition (i.e., zero resistivity is not attained) followed by a reentrant-like hump at approximately $T_mathrm{N}$ with decreasing temperature. When nonhydrostatic pressure with a uniaxial-like strain component is applied using a solid pressure medium, the partial superconductivity is continuously observed in a wide pressure range from 1.1 GPa to 3.2 GPa.
SrxBi2Se3 is recently reported to be a superconductor derived from topological insulator Bi2Se3. It shows a maximum resistive Tc of 3.25 K at ambient pressure. We report magnetic (upto 1 GPa) and transport properties (upro 8 Gpa) under pressure for single crystalline Sr0.1Bi2Se3 superconductor. Magnetic measurements show that Tc decreases from ~2.6 K (0 GPa) to ~1.9 K (0.81 GPa). Similar behavior is observed in transport properties as well without much change in the metallic characteristics in normal state resistivity. No reentrant superconducting phase (Physical Review B 93, 144514 (2016)) is observed at high pressure. Normal state resistivity near Tc is explained by Fermi liquid model. Above 100 K, a polaronic hopping conduction mechanism with two parallel channels for current flow is indicated. Band structure calculations indicate decreasing density of states at Fermi level with pressure. In consonance with transition temperature suppression in conventional BCS low Tc superconductors, the pressure effect in SrxBi2Se3 is well accounted by pressure induced band broadening.
X-ray absorption spectroscopy (XAS) and high resolution X-ray diffraction are combined to study the interplay between electronic and lattice structures in controlling the superconductivity in cuprates with a model charge-compensated CaxLa1-xBa1.75-xLa0.25+xCu3Oy (0<x<0.5, y=7.13) system. In spite of a large change in Tc, the doped holes, determined by the Cu L and O K XAS, hardly show any variation with the x. On the other hand, the CuO2 plaquette size shows a systematic change due to different size of substituted cations. The results provide a direct evidence for the chemical pressure being a key parameter for controlling the superconducting ground state of the cuprates.