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Register a new userFirst detection of the pre-biotic molecule glycolonitrile (HOCH2CN) in the interstellar medium
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Theories of a pre-RNA world suggest that glycolonitrile (HOCH$_2$CN) is a key species in the process of ribonucleotide assembly, which is considered as a molecular precursor of nucleic acids. In this Letter, we report the first detection of this pre-biotic molecule in the interstellar medium (ISM) by using ALMA data obtained at frequencies between 86.5$,$GHz and 266.5$,$GHz toward the Solar-type protostar IRAS16293-2422 B. A total of 15 unblended transitions of HOCH$_2$CN were identified. Our analysis indicates the presence of a cold (T$rm _{ex}$=24$pm$8$,$K) and a warm (T$rm _{ex}$=158$pm$38$,$K) component meaning that this molecule is present in both the inner hot corino and the outer cold envelope of IRAS16293 B. The relative abundance with respect to H$_2$ is (6.5$pm$0.6)$times$10$^{-11}$ and $geq$(6$pm$2)$times$10$^{-10}$ for the warm and cold components respectively. Our chemical modelling seems to underproduce the observed abundance for both the warm and cold component under various values of the cosmic-ray ionisation rate ($zeta$). Key gas phase routes for the formation of this molecule might be missing in our chemical network.
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In recent years, a plethora of high spectral resolution observations of sub-mm and FIR transitions of methylidene (CH), have demonstrated this radical to be a valuable proxy for H2, that can be used for characterising molecular gas within the interstellar medium (ISM) on a Galactic scale, including the CO-dark component. Here we report the discovery of the 13CH isotopologue in the ISM using the upGREAT receiver on board SOFIA. We have detected the three hyperfine structure components of the 2THz frequency transition from its ground-state toward four high-mass star-forming regions and determine 13CH column densities. The ubiquity of molecules containing carbon in the ISM has turned the determination of the ratio between the abundances of carbons two stable isotopes, 12C/13C, into a cornerstone for Galactic chemical evolution studies. Whilst displaying a rising gradient with Galactocentric distance, this ratio, when measured using observations of different molecules (CO, H2CO, and others) shows systematic variations depending on the tracer used. These observed inconsistencies may arise from optical depth effects, chemical fractionation or isotope-selective photo-dissociation. Formed from C+ either via UV-driven or turbulence-driven chemistry, CH reflects the fractionation of C+, and does not show any significant fractionation effects unlike other molecules previously used to determine the 12C/13C isotopic ratio which make it an ideal tracer for the 12C/13C ratio throughout the Galaxy. Therefore, by comparing the derived column densities of 13CH with previously obtained SOFIA data of the corresponding transitions of the main isotopologue 12CH, we derive 12C/13C isotopic ratios toward Sgr B2(M), G34.26+0.15, W49(N) and W51E. Adding our values derived from 12/13CH to previous calculations of the Galactic isotopic gradient we derive a revised value of 12C/13C = 5.85(0.50)R_GC + 15.03(3.40).
We present the first detection of gas phase S2H in the Horsehead, a moderately UV-irradiated nebula. This confirms the presence of doubly sulfuretted species in the interstellar medium and opens a new challenge for sulfur chemistry. The observed S2H abundance is ~5x10$^{-11}$, only a factor 4-6 lower than that of the widespread H2S molecule. H2S and S2H are efficiently formed on the UV-irradiated icy grain mantles. We performed ice irradiation experiments to determine the H2S and S2H photodesorption yields. The obtained values are ~1.2x10$^{-3}$ and <1x10$^{-5}$ molecules per incident photon for H2S and S2H, respectively. Our upper limit to the S2H photodesorption yield suggests that photo-desorption is not a competitive mechanism to release the S2H molecules to the gas phase. Other desorption mechanisms such as chemical desorption, cosmic-ray desorption and grain shattering can increase the gaseous S2H abundance to some extent. Alternatively, S2H can be formed via gas phase reactions involving gaseous H2S and the abundant ions S+ and SH+. The detection of S2H in this nebula could be therefore the result of the coexistence of an active grain surface chemistry and gaseous photo-chemistry.
The largest non-cyclic molecules detected in the interstellar medium (ISM) are organic with a straight-chain carbon backbone. We report an interstellar detection of a branched alkyl molecule, iso-propyl cyanide (i-C3H7CN), with an abundance 0.4 times that of its straight-chain structural isomer. This detection suggests that branched carbon-chain molecules may be generally abundant in the ISM. Our astrochemical model indicates that both isomers are produced within or upon dust grain ice mantles through the addition of molecular radicals, albeit via differing reaction pathways. The production of iso-propyl cyanide appears to require the addition of a functional group to a non-terminal carbon in the chain. Its detection therefore bodes well for the presence in the ISM of amino acids, for which such side-chain structure is a key characteristic.
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Cyanogen (NCCN) is the simplest member of the dicyanopolyynes group, and has been proposed as a major source of the CN radical observed in cometary atmospheres. Although not detected through its rotational spectrum in the cold interstellar medium, this very stable species is supposed to be very abundant. The chemistry of cyanogen in the cold interstellar medium can be investigated through its metastable isomer, CNCN (isocyanogen). Its formation may provide a clue on the widely abundant CN radical observed in cometary atmospheres. We performed an unbiased spectral survey of the L1544 proto-typical prestellar core, using the IRAM-30m and have analysed, for this paper, the nitrogen chemistry that leads to the formation of isocyanogen. We report on the first detection of CNCN, NCCNH+, C3N, CH3CN, C2H3CN, and H2CN in L1544. We built a detailed chemical network for NCCN/CNCN/HC2N2+ involving all the nitrogen bearing species detected (CN, HCN, HNC, C3N, CNCN, CH3CN, CH2CN, HCCNC, HC3N, HNC3, H2CN, C2H3CN, HCNH+, HC3NH+) and the upper limits on C4N, C2N. The main cyanogen production pathways considered in the network are the CN + HNC and N + C3N reactions. The comparison between the observations of the nitrogen bearing species and the predictions from the chemical modelling shows a very good agreement, taking into account the new chemical network. The expected cyanogen abundance is greater than the isocyanogen abundance by a factor of 100. Although cyanogen cannot be detected through its rotational spectrum, the chemical modelling predicts that it should be abundant in the gas phase and hence might be traced through the detection of isocyanogen. It is however expected to have a very low abundance on the grain surfaces compared to HCN.
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