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Determining the Superconducting Transition Temperatures of Liquids

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 Added by Junren Shi
 Publication date 2019
  fields Physics
and research's language is English




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We develop a non-perturbative approach for calculating the superconducting transition temperatures ($T_{c}$) of liquids. The electron-electron scattering amplitude induced by electron-phonon coupling (EPC), from which the effective pairing interaction can be inferred, is related to the fluctuation of the $T$-matrix of electron scattering induced by ions. By applying the relation, EPC parameters can be extracted from a path-integral molecular dynamics simulation. For determining $T_{c}$, the linearized Eliashberg equations are re-established in the non-perturbative context. We apply the approach to estimate $T_{c}$ of metallic hydrogen liquids. It indicates that metallic hydrogen liquids in the pressure regime from $0.5$ to $1.5mathrm{,TPa}$ have $T_{c}$ well above their melting temperatures, therefore are superconducting liquids.



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The quantum critical Antiferromagnetic (AFM) fluctuation spectra measured by inelastic neutron scattering recently in two heavy fermion superconductors are used together with their other measured properties to calculate their D-wave superconducting transition temperatures $T_{rm c}$. To this end, the linearized Eliashberg equations for D-wave superconductivity induced by AFM fluctuations are solved in models of fermions with various levels of nesting. The results for the ratio of $T_{rm c}$ to the characteristic spin-fluctuation energy are well parametrized by a dimensionless coupling constant and the AFM correlation length. Comparing the results with experiments suggests that one may reasonably conclude that superconductivity in these compounds is indeed caused by AFM fluctuations. This conclusion is strengthened by a calculation with the same parameters of the measured coefficient of the normal state quantum-critical resistivity $propto T^{3/2}$ characteristic of {it gaussian} AFM quantum-critical fluctuations. The calculations give details of the superconducting coupling as a function of the correlation length and the integrated fluctuation spectra useful in other compounds.
In a recent contribution to this journal, it was shown that the transition temperatures of optimal high-Tc compounds obey the algebraic relation, Tc0 = kB-1{beta}/ell{zeta}, where ell is related to the mean spacing between interacting charges in the layers, {zeta} is the distance between interacting electronic layers, {beta} is a universal constant and kB is Boltzmanns constant. The equation was derived assuming pairing based on interlayer Coulomb interactions between physically separated charges. This theory was initially validated for 31 compounds from five different high-Tc families (within an accuracy of pm1.37 K). Herein we report the addition of Fe1+xSe1-y and Fe1+xSe1-yTey (both optimized under pressure) and AzFe2-xSe2 (for A = K, Rb, or Cs) to the growing list of Coulomb-mediated superconducting compounds in which Tc0 is determined by the above equation. Doping in these materials is accomplished through the introduction of excess Fe and/or Se deficiency, or a combination of alkali metal and Fe vacancies. Consequently, a very small number of vacancies or interstitials can induce a superconducting state with a substantial transition temperature. The confirmation of the above equation for these Se-based Fe chalcogenides increases to six the number of superconducting families for which the transition temperature can be accurately predicted.
We derive analytic expressions for the critical temperatures of the superconducting (SC) and pseudogap (PG) transitions of the high-Tc cuprates as a function of doping. These are in excellent agreement with the experimental data both for single-layered materials such as LSCO, Bi2201 and Hg1201 and multi-layered ones, such as Bi2212, Bi2223, Hg1212 and Hg1223. Optimal doping occurs when the chemical potential vanishes, thus leading to an universal expression for the optimal SC transition temperatures. This allows for the obtainment of a quantitative description of the growth of such temperatures with the number of layers, N, which accurately applies to the $Bi$, $Hg$ and $Tl$ families of cuprates. We study the pressure dependence of the SC transition temperatures, obtaining excellent agreement with the experimental data for different materials and dopings. These results are obtained from an effective Hamiltonian for the itinerant oxygen holes, which includes both the electric repulsion between them and their magnetic interactions with the localized copper ions. We show that the former interaction is responsible for the SC and the latter, for the PG phases, the phase diagram of cuprates resulting from the competition of both. The Hamiltonian is defined on a bipartite oxygen lattice, which results from the fact that only the $p_x$ and $p_y$ oxygen orbitals alternatively hybridize with the $3d$ copper orbitals. From this, we can provide an unified explanation for the $d_{x^2-y^2}$ symmetry of both the SC and PG order parameters and obtain the Fermi pockets observed in ARPES experiments.
Here we report the observation of pressure-induced superconductivity in type-II Weyl semimetal (WSM) candidate NbIrTe4 and the evolution of its Hall coefficient (RH), magnetoresistance (MR), and lattice with increasing pressure to ~57 GPa. These results provide a significant opportunity to investigate the universal high-pressure behavior of ternary WSMs, including the sister compound TaIrTe4 that has been known through our previous studies. We find that the pressure-tuned evolution from the WSM to the superconducting (SC) state in these two compounds exhibit the same trend, i.e., a pressure-induced SC state emerges from the matrix of the non-superconducting WSM state at ~ 27 GPa, and then the WSM state and the SC state coexist up to 40 GPa. Above this pressure, an identical high-pressure behavior, characterized by almost the same value of RH and MR in its normal state and the same value of Tc in its SC state, appears in both compounds. Our results not only reveal a universal connection between the WSM state and SC state, but also demonstrate that NbIrTe4 and TaIrTe4 can make the same contribution to the normal and SC states that inhabit in the high-pressure phase, although these two compounds have dramatically different topological band structure at ambient pressure.
101 - C.M. Varma 2010
An overview of the momentum and frequency dependence of effective electron-electron interactions which favor electronic instability to a superconducting state in the angular-momentum channel $ell$ and the properties of the interactions which determine $T_c$ is provided. Both interactions induced through exchange of phonons as well as purely electronic fluctuations of spin density, charge density or current density are considered. Special attention is paid to the role of quantum critical fluctuations including pairing due to their virtual exchange as well as de-pairing due to inelastic scattering. In light of the above, empirical data and theory specific to phonon induced superconductivity, in cold atoms, superfluidity in liquid $He^3$, superconductivity in some of the heavy fermion compounds, in Cuprates, in pncitides and the valence skipping compound, is reviewed. The physical basis for the following observation is provided: The universal ratio of s-wave $T_c$ to Fermi-energy for fermions at the unitarity limit with attractive interactions is about 0.15, the ratio of the maximum $T_c$ to the typical phonon frequency in phonon induced s-wave superconductivity is of the same order; the ratio of p-wave $T_c$ to the renormalized Fermi-energy in liquid $He^3$, a very strongly correlated Fermi-liquid near its melting pressure, is only $O(10^{-3})$; in the Cuprates and the heavy-fermions where d-wave superconductivity occurs in a region governed by a special class of quantum-critical fluctuations, this ratio rises to $O(10^{-2})$. These discussions also suggest factors important for obtaining higher $T_c$.
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