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Register a new user${}^{239}$Pu nuclear magnetic resonance in the candidate topological insulator PuB$_4$
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We present a detailed nuclear magnetic resonance (NMR) study of ${}^{239}$Pu in bulk and powdered single-crystal plutonium tetraboride (PuB$_4$), which has recently been investigated as a potential correlated topological insulator. This study constitutes the second-ever observation of the ${}^{239}$Pu NMR signal, and provides unique on-site sensitivity to the rich $f$-electron physics and insight into the bulk gap-like behavior in PuB$_4$. The ${}^{239}$Pu NMR spectra are consistent with axial symmetry of the shift tensor showing for the first time that ${}^{239}$Pu NMR can be observed in an anisotropic environment and up to room temperature. The temperature dependence of the ${}^{239}$Pu shift, combined with a relatively long spin-lattice relaxation time ($T_1$), indicate that PuB$_4$ adopts a non-magnetic state with gap-like behavior consistent with our density functional theory (DFT) calculations. The temperature dependencies of the NMR Knight shift and $T_1^{-1}$--microscopic quantities sensitive only to bulk states--imply bulk gap-like behavior confirming that PuB$_4$ is a good candidate topological insulator. The large contrast between the ${}^{239}$Pu orbital shifts in the ionic insulator PuO$_2$ ($sim$~+24.7~%) and PuB$_4$ ($sim$~-0.5~%) provides a new tool to investigate the nature of chemical bonding in plutonium materials.
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A topological insulator is a state of matter which does not break any symmetry and is characterized by topological invariants, the integer expectation values of non-local operators. Antiferromagnetism on the other hand is a broken symmetry state in which the translation symmetry is reduced and time reversal symmetry is broken. Can these two phenomena coexist in the same material? A proposal by Mong {it et al.}cite{Mong2010} asserts that the answer is yes. Moreover, it is theoretically possible that the onset of antiferromagnetism enables the non-trivial topology since it may create spin-orbit coupling effects which are absent in the non-magnetic phase. The current work examines a real system, half-Heusler GdBiPt, as a candidate for topological anti ferromagnetism. We find that the magnetic moments of the gadolinium atoms form ferromagnetic sheets which are stacked antiferromagnetically along the body diagonal. This magnetic structure may induce spin orbit coupling on band electrons as they hop perpendicular to the ferromagnetic sheets.
In this work, we report nuclear magnetic resonance (NMR) combined with density functional theory (DFT) studies of the transition metal dichalcogenide ZrTe$_2$. The measured NMR shift anisotropy reveals a quasi-2D behavior connected to a topological nodal line close to the Fermi level. With the magnetic field perpendicular to the ZrTe$_2$ layers, the measured shift can be well-fitted by a combination of enhanced diamagnetism and spin shift due to high mobility Dirac electrons. The spin-lattice relaxation rates with external field both parallel and perpendicular to the layers at low temperatures match the expected behavior associated with extended orbital hyperfine interaction due to quasi-2D Dirac carriers. In addition, calculated band structures also show clear evidence for the existence of nodal line in ZrTe$_2$ between $Gamma$ and A. For intermediate temperatures, there is a sharp reduction in spin-lattice relaxation rate which can be explained as due to a reduced lifetime for these carriers, which matches the reported large change in mobility in the same temperature range. Above 200 K, the local orbital contribution starts to dominate in an orbital relaxation mechanism revealing the mixture of atomic functions.
We report a detailed study of the transport coefficients of $beta$-Bi$_4$I$_4$ quasi-one dimensional topological insulator. Electrical resistivity, thermoelectric power, thermal conductivity and Hall coefficient measurements are consistent with the possible appearance of a charge density wave order at low temperatures. Both electrons and holes contribute to the conduction in $beta$-Bi$_4$I$_4$ and the dominant type of charge carrier changes with temperature as a consequence of temperature-dependent carrier densities and mobilities. Measurements of resistivity and Seebeck coefficient under hydrostatic pressure up to 2 GPa show a shift of the charge density wave order to higher temperatures suggesting a strongly one-dimensional character at ambient pressure. Surprisingly, superconductivity is induced in $beta$-Bi$_4$I$_4$ above 10 GPa with of 4.0 K which is slightly decreasing upon increasing the pressure up to 20 GPa. Chemical characterisation of the pressure-treated samples shows amorphization of $beta$-Bi$_4$I$_4$ under pressure and rules out decomposition into Bi and BiI$_3$ at room-temperature conditions.
We present nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements performed on single crystalline ccag{}, a member of a recently discovered family of heavy fermion materials Ce$_2M$Al$_7$Ge$_4$ ($M$ = Co, Ir, Ni, or Pd). Previous measurements indicated a strong Kondo interaction as well as magnetic order below $T_M = 1.8$ K. Our NMR spectral measurements show that the Knight shift $K$ is proportional to the bulk magnetic susceptibility $chi$ at high temperatures. A clear Knight shift anomaly ($K otpropto chi$) is observed at coherence temperatures $T^* sim 17.5$ K for $H_0 parallel hat{c}$ and 10 K for $H_0 parallel hat{a}$ at the ${}^{59}$Co site, and $T^* sim 12.5$ K at the ${}^{27}$Al(3) site for $H_0 parallel hat{a}$ characteristic of the heavy fermion nature of this compound. At high temperatures the ${}^{59}$Co NMR spin-lattice relaxation rate $T_1^{-1}$ is dominated by spin fluctuations of the 4$f$ local moments with a weak metallic background. The spin fluctuations probed by ${}^{59}$Co NMR are anisotropic and larger in the basal plane than in the $c$ direction. Furthermore, we find $(T_1TK)^{-1} propto T^{-1/2}$ at the ${}^{59}$Co site as expected for a Kondo system for $T > T^*$ and $T> T_K$. ${}^{59}$Co NQR slrr{} measurements at low temperatures indicate slowing down of spin fluctuations above the magnetic ordering temperature $T_M sim 1.8$ K. A weak ferromagnetic character of fluctuations around $mathbf{q}=0$ is evidenced by an increase of $chi T$ versus $T$ above the magnetic ordering temperature. We also find good agreement between the observed and calculated electric field gradients at all observed sites.
We report the discovery of topological magnetism in the candidate magnetic Weyl semimetal CeAlGe. Using neutron scattering we find this system to host several incommensurate, square-coordinated multi-$vec{k}$ magnetic phases below $T_{rm{N}}$. The topological properties of a phase stable at intermediate magnetic fields parallel to the $c$-axis are suggested by observation of a topological Hall effect. Our findings highlight CeAlGe as an exceptional system for exploiting the interplay between the nontrivial topologies of the magnetization in real space and Weyl nodes in momentum space.
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