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Register a new userNormal-state properties of the antiperovskite oxide Sr$_{3-x}$SnO revealed by $^{119}$Sn-NMR
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We have performed $^{119}$Sn-NMR measurements on the antiperovskite oxide superconductor Sr$_{3-x}$SnO to investigate how its normal state changes with the Sr deficiency. A two-peak structure was observed in the NMR spectra of all the measured samples. This suggests that the phase separation tends to occur between the nearly stoichiometric and heavily Sr-deficient Sr$_{3-x}$SnO phases. The measurement of the nuclear spin-lattice relaxation rate $1/T_1$ indicates that the Sr-deficient phase shows a conventional metallic behavior due to the heavy hole doping. In contrast, the nearly stoichiometric phase exhibits unusual temperature dependence of $1/T_1$, attributable to the presence of a Dirac-electron band.
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A large variety of perovskite oxide superconductors are known, including some of the most prominent high-temperature and unconventional superconductors. However, superconductivity among the oxidation state inverted material class, the antiperovskite oxides, was reported just recently for the first time. In this superconductor, Sr$_{3-x}$SnO, the unconventional ionic state Sn$^{4-}$ is realized and possible unconventional superconductivity due to a band inversion has been discussed. Here, we discuss an improved facile synthesis method, making it possible to control the strontium deficiency in Sr$_{3-x}$SnO. Additionally, a synthesis method above the melting point of Sr$_{3}$SnO is presented. We show temperature dependence of magnetization and electrical resistivity for superconducting strontium deficient Sr$_{3-x}$SnO ($T_{mathrm{c}}$ ~ 5 K) and for Sr$_{3}$SnO without a superconducting transition down to 0.15 K. Further, we reveal a significant effect of strontium raw material purity on the superconductivity and achieve 40% increased superconducting volume fraction (~100%) compared to the highest value reported so far. More detailed characterisation utilising powder X-ray diffraction and energy-dispersive X-ray spectroscopy show that a minor cubic phase, previously suggested to be a Sr$_{3-x}$SnO, is SrO. The improved characterization and controlled synthesis reported herein enable detailed investigations on the superconducting nature and its dependency on the strontium deficiency in Sr$_{3-x}$SnO.
We report a $mu$SR study on the antiperovskite oxide superconductor Sr$_{3-x}$SnO. With transverse-field $mu$SR, we observed the increase of the muon relaxation rate upon cooling below the superconducting transition temperature $T_{mathrm{c}}=5.4$ K, evidencing bulk superconductivity. The exponential temperature dependence of the relaxation rate $sigma$ at low temperatures suggests a fully gapped superconducting state. We evaluated the zero-temperature penetration depth $lambda(0)propto1/sqrt{sigma(0)}$ to be around 320-1020 nm. Such a large value is consistent with the picture of a doped Dirac semimetal. Moreover, we revealed that the ratio $T_{mathrm{c}}/lambda(0)^{-2}$ is larger than those of ordinary superconductors and is comparable to those of unconventional superconductors. The relatively high $T_{mathrm{c}}$ for small carrier density may hint at an unconventional pairing mechanism beyond the ordinary phonon-mediated pairing. In addition, zero-field $mu$SR did not provide evidence of broken time-reversal symmetry in the superconducting state. These features are consistent with the theoretically proposed topological superconducting state in Sr$_{3-x}$SnO, as well as with $s$-wave superconductivity.
We report the temperature variation of the $^{119}$Sn-M{o}ssbauer spectra of the antiperovskite (inverse perovskite) oxide superconductor Sr$_{3-x}$SnO. Both superconductive (Sr-deficient) and non-superconductive (nearly stoichiometric) samples exhibit major $gamma$-ray absorption with isomer shift similar to that of Mg$_2$Sn. This fact shows that Sr$_{3-x}$SnO contains the metallic anion Sn$^{4-}$, which is rare especially among oxides. In both samples, we observed another $gamma$-ray absorption with a larger isomer shift, indicating that there is another ionic state of Sn with a higher oxidation number. The temperature dependence of the absorption intensities reveals that the Sn ions exhibiting larger isomer shifts have a lower energy of the local vibration. The larger isomer shift and lower vibration energy are consistent with the values estimated from the first-principles calculations for hypothetical structures with various Sr-deficiency arrangements. Therefore, we conclude that the additional $gamma$-ray absorptions originate from the Sn atoms neighboring the Sr deficiency.
A rapid decrease in the critical current density (Jc) of YBa2Cu3O7-x (YBCO) films with increasing film thickness has been observed for multiple YBCO growth processes. While such behavior is predicted from 2D collective pinning models under certain assumptions, empirical observations of the thickness dependence of Jc are believed to be largely processing dependent at present. To investigate this behavior in ex situ YBCO films, 2.0 and 2.9 um thick YBCO films on ion beam assisted deposition (IBAD) - yttria stabilized zirconia (YSZ) substrates were thinned and repeatedly measured for rho(T) and Jc(H). The 2.9 um film exhibited a constant Jc(77K,SF) through thickness of ~1 MA/cm2 while the 2.0 um film exhibited an increase in Jc(77K,SF) as it was thinned. Neither film offered evidence of significant dead layers, suggesting that further increases in critical current can be obtained by growing thicker YBCO layers.
We report 139La, 57Fe and 75As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements on powders of the new LaO1-xFxFeAs superconductor for x = 0 and x = 0.1 at temperatures up to 480 K, and compare our measured NQR spectra with local density approximation (LDA) calculations. For all three nuclei in the x = 0.1 material, it is found that the local Knight shift increases monotonically with an increase in temperature, and scales with the macroscopic susceptibility, suggesting a single magnetic degree of freedom. Surprisingly, the spin lattice relaxation rates for all nuclei also scale with one another, despite the fact that the form factors for each site sample different regions of q-space. This result suggests a lack of any q-space structure in the dynamical spin susceptibility that might be expected in the presence of antiferromagnetic correlations. Rather, our results are more compatible with simple quasi-particle scattering. Furthermore, we find that the increase in the electric field gradient at the As cannot be accounted for by LDA calculations, suggesting that structural changes, in particular the position of the As in the unit cell, dominate the NQR response.
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