Within the framework of the perturbative QCD approach, we calculate the time-like $B_cB_c(B_c^*)$ form factors $F(Q^2)$ and $A_2(Q^2)$. We include relativistic corrections and QCD corrections, either of which can give about $20%$ correction to the leading-order contribution, but there are cancellation effects between them. We calculate the cross sections of the $e^+e^-to B_c^-B_c^+(B_c^{*+})$ processes. The cross sections are enhanced at the $Z$ pole to be $sigma^{PP}(Q=m_Z) sim 1.3times10^{-5}text{pb}$ and $sigma^{PV}(Q=m_Z) sim 2.5times10^{-5}text{pb}$, which are still too small to be detected by proposed $e^+e^-$ colliders such as the Circular Electron Positron Collider.