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Register a new userQuantum entanglement shared in hydrogen bonds and its usage as a resource in molecular recognition
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Quantum tunneling events occurring through biochemical bonds are capable to generate quantum correlations between bonded systems, which in turn makes the conventional second law of thermodynamics approach insufficient to investigate these systems. This means that the utilization of these correlations in their biological functions could give an evolutionary advantage to biomolecules to an extent beyond the predictions of molecular biology that are generally based on the second law in its standard form. To explore this possibility, we first compare the tunneling assisted quantum entanglement shared in the ground states of covalent and hydrogen bonds. Only the latter appears to be useful from a quantum information point of view. Also, significant amounts of quantum entanglement can be found in the thermal state of hydrogen bond. Then, we focus on an illustrative example of ligand binding in which a receptor protein or an enzyme is restricted to recognize its ligands using the same set of proton-acceptors and donors residing on its binding site. In particular, we show that such a biomolecule can discriminate between $3^n - 1$ agonist ligands if it uses the entanglement shared in $n$ intermolecular hydrogen bonds as a resource in molecular recognition. Finally, we consider the molecular recognition events encountered in both the contemporary genetic machinery and its hypothetical primordial ancestor in pre-DNA world, and discuss whether there may have been a place for the utilization of quantum entanglement in the evolutionary history of this system.
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Complete measurements, while providing maximal information gain, results in destruction of the shared entanglement. In the standard teleportation scheme, the senders measurement on the shared entangled state between the sender and the receiver has that consequence. We propose here a teleportation scheme involving weak measurements which can sustain entanglement upto a certain level so that the reusability of the shared resource state is possible. The measurements are chosen in such a way that it is weak enough to retain entanglement and hence can be reused for quantum tasks, yet adequately strong to ensure quantum advantage in the protocol. In this scenario, we report that at most six sender-receiver duos can reuse the state, when the initial shared state is entangled in a finite neighborhood of the maximally entangled state and for a suitable choice of weak measurements. However, we observe that the reusability number decreases with the decrease in the entanglement of the initial shared state. Among the weakening strategies studied, Bell measurement admixed with white noise performs better than any other low-rank weak measurements in this situation.
We show that one-body entanglement, which is a measure of the deviation of a pure fermionic state from a Slater determinant (SD) and is determined by the mixedness of the single-particle density matrix (SPDM), can be considered as a quantum resource. The associated theory has SDs and their convex hull as free states, and number conserving fermion linear optics operations (FLO), which include one-body unitary transformations and measurements of the occupancy of single-particle modes, as the basic free operations. We first provide a bipartitelike formulation of one-body entanglement, based on a Schmidt-like decomposition of a pure $N$-fermion state, from which the SPDM [together with the $(N-1)$-body density matrix] can be derived. It is then proved that under FLO operations, the initial and postmeasurement SPDMs always satisfy a majorization relation, which ensures that these operations cannot increase, on average, the one-body entanglement. It is finally shown that this resource is consistent with a model of fermionic quantum computation which requires correlations beyond antisymmetrization. More general free measurements and the relation with mode entanglement are also discussed.
The development of spectroscopic techniques able to detect and verify quantum coherence is a goal of increasing importance given the rapid progress of new quantum technologies, the advances in the field of quantum thermodynamics, and the emergence of new questions in chemistry and biology regarding the possible relevance of quantum coherence in biochemical processes. Ideally, these tools should be able to detect and verify the presence of quantum coherence in both the transient dynamics and the steady state of driven-dissipative systems, such as light-harvesting complexes driven by thermal photons in natural conditions. This requirement poses a challenge for standard laser spectroscopy methods. Here, we propose photon correlation measurements as a new tool to analyse quantum dynamics in molecular aggregates in driven-dissipative situations. We show that the photon correlation statistics on the light emitted by a molecular dimer model can signal the presence of coherent dynamics. Deviations from the counting statistics of independent emitters constitute a direct fingerprint of quantum coherence in the steady state. Furthermore, the analysis of frequency resolved photon correlations can signal the presence of coherent dynamics even in the absence of steady state coherence, providing direct spectroscopic access to the much sought-after site energies in molecular aggregates.
We develop a resource theory of symmetric distinguishability, the fundamental objects of which are elementary quantum information sources, i.e., sources that emit one of two possible quantum states with given prior probabilities. Such a source can be represented by a classical-quantum state of a composite system $XA$, corresponding to an ensemble of two quantum states, with $X$ being classical and $A$ being quantum. We study the resource theory for two different classes of free operations: $(i)$ ${rm{CPTP}}_A$, which consists of quantum channels acting only on $A$, and $(ii)$ conditional doubly stochastic (CDS) maps acting on $XA$. We introduce the notion of symmetric distinguishability of an elementary source and prove that it is a monotone under both these classes of free operations. We study the tasks of distillation and dilution of symmetric distinguishability, both in the one-shot and asymptotic regimes. We prove that in the asymptotic regime, the optimal rate of converting one elementary source to another is equal to the ratio of their quantum Chernoff divergences, under both these classes of free operations. This imparts a new operational interpretation to the quantum Chernoff divergence. We also obtain interesting operational interpretations of the Thompson metric, in the context of the dilution of symmetric distinguishability.
Just recently, complementarity relations (CRs) have been derived from the basic rules of Quantum Mechanics. The complete CRs are equalities involving quantum coherence, $C$, quantum entanglement, and predictability, $P$. While the first two are already quantified in the resource theory framework, such a characterization lacks for the last. In this article, we start showing that, for a system prepared in a state $rho$, $P$ of $rho$, with reference to an observable $X$, is equal to $C$, with reference to observables mutually unbiased (MU) to $X$, of the state $Phi_{X}(rho)$, which is obtained from a non-revealing von Neumann measurement (NRvNM) of $X$. We also show that $P^X(rho)>C^{Y}(Phi_{X}(rho))$ for observables not MU. Afterwards, we provide quantum circuits for implementing NRvNMs and use these circuits to experimentally test these (in)equalities using the IBMs quantum computers. Furthermore, we give a resource theory for predictability, identifying its free quantum states and free quantum operations and discussing some predictability monotones. Besides, after applying one of these predictability monotones to study bipartite systems, we discuss the relation among the resource theories of quantum coherence, predictability, and purity.
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