We present a large-scale galaxy structure Cl J021734-0513 at z~0.65 discovered in the UKIDSS UDS field, made of ~20 galaxy groups and clusters, spreading over 10 Mpc. We report on a VLT/VIMOS spectroscopic follow-up program that, combined with past spectroscopy, allowed us to confirm four galaxy clusters (M200 ~ 10^14 Msol) and a dozen associated groups and star-forming galaxy overdensities. Two additional filamentary structures at z ~ 0.62 and z ~ 0.69 and foreground and background clusters at 0.6 < z < 0.7 were also confirmed along the line-of-sight. The structure subcomponents are at different formation stages. The clusters have a core dominated by passive galaxies and an established red sequence. The remaining structures are a mix of star-forming galaxy overdensities and forming groups. The presence of quiescent galaxies in the core of the latter shows that `preprocessing has already happened before the groups fall into their more massive neighbours. Our spectroscopy allows us to derive spectral index measurements e.g. emission/absorption line equivalent widths, strength of the 4000A break, valuable to investigate the star formation history of structure members. Based on these line measurements, we select a population of `poststarburst galaxies. These galaxies are preferentially found within the virial radius of clusters, supporting a scenario in which their recent quenching could be prompted by gas stripping by the dense intracluster medium. We derive stellar age estimates using MCMC-based spectral fitting for quiescent galaxies and find a correlation between ages and colours/stellar masses which favours a top-down formation scenario of the red sequence. A catalogue of ~650 redshifts in UDS will be released alongside the paper.
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